Static and Ultrafast Optical Response of Two Ag Nanospheres Glued by a CdTe Quantum Dot

TL;DR

This study demonstrates the placement of a CdTe quantum dot between two silver nanospheres, revealing ultrafast optical responses and potential applications in plasmonic sensing and nano-optics.

Contribution

It introduces a method to position a semiconductor quantum dot between silver nanospheres and investigates its ultrafast optical effects.

Findings

Enhanced local field at hot-spot by up to six orders of magnitude

Strong influence of CdTe QD on hot-spot dynamics

Potential applications in sensing and energy harvesting

Abstract

A hot-spot of high local field can be created in between two closely placed metal nanoparticles by irradiating them with an appropriate wavelength and polarization of incident light. The strength of the field at the hot-spot is expected to get enhanced by even up to six orders of magnitude than that of the applied field. Placing a semiconductor quantum dot or an analyte molecule at the hot-spot is an essential step towards harnessing the enhanced field for applications. In this article, we show that it is possible to position a CdTe quantum dot (QD) between two larger silver nanospheres in colloidal solution. The extinction spectra measured during growth suggests that the final hybrid nanostructure have two touching Ag nanoparticles (NPs) and a CdTe QD in between them close to the point of contact. Using ultrafast transient measurements, it has been shown that the presence of CdTe QD strongly influence the dynamics when the probe excites the hot-spot. The method demonstrated here to place the semiconductor QD in between the two Ag NPs is an important step in the area of colloidal self-assembly and for application of hot-spot in plasmonic sensing, optoelectronics, energy-harvesting, nanolithography, and optical nano-antennas.