Interplay of itinerant magnetism and reentrant spin-glass behavior in Fe$_{x}$Cr$_{1-x}$

TL;DR

This study investigates how doping chromium with iron affects magnetic phases, revealing a dome of reentrant spin-glass behavior near a quantum critical point, with detailed experimental characterization of magnetic and electronic properties.

Contribution

It provides a comprehensive experimental analysis of Fe$_{x}$Cr$_{1-x}$, uncovering the emergence and evolution of spin-glass behavior in an itinerant-electron system near a quantum critical point.

Findings

Identification of a spin-glass dome at 0.10 ≤ x ≤ 0.25

Increase in ferromagnetic cluster size with x

Crossover from cluster-glass to superparamagnetic behavior

Abstract

When suppressing the itinerant antiferromagnetism in chromium by doping with the isostructual itinerant ferromagnet iron, a dome of spin-glass behavior emerges around a putative quantum critical point at an iron concentration $x \approx 0.15$. Here, we report a comprehensive investigation of polycrystalline samples of Fe$_{x}$Cr$_{1-x}$ in the range $0.05 \leq x \leq 0.30$ using x-ray powder diffraction, magnetization, ac susceptibility, and neutron depolarization measurements, complemented by specific heat and electrical resistivity data for $x = 0.15$. Besides antiferromagnetic ($x < 0.15$) and ferromagnetic regimes ($0.15 \leq x$), we identify a dome of reentrant spin-glass behavior at low temperatures for $0.10 \leq x \leq 0.25$ that is preceded by a precursor phenomenon. Neutron depolarization indicates an increase of the size of ferromagnetic clusters with increasing $x$ and the Mydosh parameter $\phi$, inferred from the ac susceptibility, implies a crossover from cluster-glass to superparamagnetic behavior. Taken together, these findings consistently identify Fe$_{x}$Cr$_{1-x}$ as an itinerant-electron system that permits to study the evolution of spin-glass behavior of gradually varying character in unchanged crystalline environment.