Filling, depinning, unbinding: Three adsorption regimes for nanocorrugated substrates

TL;DR

This paper investigates the complex adsorption process on nanocorrugated substrates, identifying three regimes—filling, depinning, and unbinding—and analyzing how geometric parameters influence each stage using density functional theory.

Contribution

It introduces a detailed analysis of the three adsorption regimes on nanocorrugated surfaces, highlighting the roles of geometric features in the depinning transition using advanced theoretical models.

Findings

Depinning is governed by the width of wall pillars.

Groove width determines the location of the depinning transition.

The unbinding process involves a continuous flattening of the interface.

Abstract

We study adsorption at periodically corrugated substrates formed by scoring rectangular grooves into a planar solid wall which interacts with the fluid via long-range (dispersion) forces. The grooves are assumed to be macroscopically long but their depth, width and separations can all be molecularly small. We show that the entire adsorption process can be divided into three parts consisting of (i) \emph{filling} the grooves by a capillary liquid; (ii) \emph{depinning} of the liquid-gas interface from the wall edges; and (iii) \emph{unbinding} of the interface from the top of the wall, which is accompanied by a rapid but continuous flattening of its shape. Using a nonlocal density functional theory and mesoscopic interfacial models all the regimes are discussed in some detail to reveal the complexity of the entire process and subtle aspects that affect its behaviour. In particular, it is shown that the nature of the depinning phenomenon is governed by the width of the wall pillars (separating grooves), whilst the grooves width only controls the location of the depinning first-order transition, if present.