Atomic origin for hydrogenation promoted bulk oxygen vacancies removal in vanadium dioxide

TL;DR

This study introduces a hydrogen doping method to effectively remove oxygen vacancies in VO2 crystals at lower temperatures, enhancing defect control in metal oxides.

Contribution

It presents a novel hydrogenation-assisted annealing technique that accelerates oxygen vacancy removal in VO2, overcoming high energy barriers of traditional methods.

Findings

Hydrogen doping accelerates oxygen vacancy recovery in VO2.

Theoretical calculations show electrons from H-doping facilitate vacancy diffusion.

Method can be applied to other metal oxides for defect control.

Abstract

Oxygen vacancies (VO), a common type of point defects in metal oxides materials, play important roles on the physical and chemical properties. To obtain stoichiometric oxide crystal, the pre-existing VO is always removed via careful post-annealing treatment at high temperature in air or oxygen atmosphere. However, the annealing conditions is difficult to control and the removal of VO in bulk phase is restrained due to high energy barrier of VO migration. Here, we selected VO2 crystal film as the model system and developed an alternative annealing treatment aided by controllable hydrogen doping, which can realizes effective removal of VO defects in VO2-{\delta} crystal at lower temperature. This finding is attributed to the hydrogenation accelerated oxygen vacancies recovery in VO2-{\delta} crystal. Theoretical calculations revealed that the H-doping induced electrons are prone to accumulate around the oxygen defects in VO2-{\delta} film, which facilitates the diffusion of VO and thus makes it easier to be removed. The methodology is expected to be applied to other metal oxides for oxygen-related point defects control.