Excitations in the spin-1 trimer chain compound CaNi3P4O14: gapped dispersive spinwaves to gapless magnetic excitations

TL;DR

This study investigates magnetic excitations in CaNi3P4O14, revealing gapped spin waves below the ordering temperature and gapless excitations above, with detailed analysis of exchange interactions and anisotropy using neutron scattering and theoretical modeling.

Contribution

The paper provides a comprehensive experimental and theoretical analysis of exchange interactions and magnetic excitations in a spin-1 trimer chain compound, highlighting the role of anisotropy and interchain coupling.

Findings

Gapped dispersive spin waves observed below 16 K

Gapless magnetic excitations observed above 16 K

Exchange interactions J1, J2, J3 characterized and compared with DFT calculations

Abstract

Magnetic excitations and the spin Hamiltonian of the spin-1 J1-J1-J2 trimer chain compound CaNi3P4O14 have been investigated by inelastic neutron scattering. Experimental data reveal gapped dispersive spin wave excitations in the 3D long-range ordered magnetic state (TC = 16 K), and gapless magnetic excitations above the TC. Simulated magnetic excitations, by using the linear spin wave theory, for a model of coupled trimer spin-chains provide a good description of the observed experimental data. The analysis reveals both ferromagnetic J1 and J2 interactions within the chains, and an antiferromagnetic interchain interaction J3 between chains. The strengths of the J1 and J2 are found to be closer (J2/J1 ~ 0.81), and J3 is determined to be weaker (J3/ J1 ~ 0.69), which is consistent with the spin chain type crystal structure. Presence of a weak single-ion-anisotropy (D/J=0.19) is also revealed. The strengths and signs of exchange interactions explain why the 1/3 magnetization is absent in the studied spin-1 compound CaNi3P4O14 in contrast to its S= 5/2 counterpart Mn based isostructural compound. The signs of the exchange interactions are in agreement with that obtained from the reported DFT calculations, whereas, their strengths are found to be significantly different. The relatively strong value of the J3 in CaNi3P4O14 gives a conventional 3D type magnetic ordering below the TC, however, retains its 1D character above the TC. The present experimental study also reveals a sharp change of single-ion anisotropy across the TC indicating that the stability of the 3D magnetic ordering in CaNi3P4O14 is ascribed to the local magnetic anisotropy in addition to interchain interactions. The present study divulges the importance of full knowledge of the exchange interactions in trimer spin chain compounds to understand their exotic magnetic properties, such as 1/3 magnetization plateau.