Improved Thermoelectric Properties in (1-x)LaCoO3/(x)La0.7Sr0.3CoO3 Composite

TL;DR

This study demonstrates that creating composites of LaCoO3 with La0.7Sr0.3CoO3 significantly enhances thermoelectric performance by increasing the figure-of-merit (zT) through improved Seebeck coefficient and reduced thermal conductivity, especially at high temperatures.

Contribution

The paper introduces a composite approach to improve thermoelectric properties of LaCoO3 by adding La0.7Sr0.3CoO3, leading to a fivefold increase in zT at 800 K.

Findings

Five times improvement in zT at 800 K.

Enhanced Seebeck coefficient due to oxygen vacancies.

Reduced thermal conductivity from phonon scattering.

Abstract

A high Seebeck coefficient (S), large electrical conductivity ({\sigma}), and reduced thermal conductivity ({\kappa}) are required to achieve a high figure-of-merit (zT) in an ideal thermoelectric (TE) system, which is challenging in a single system due to the interdependence of TE parameters. Composite approach is promising to manipulate the TE parameters. In this study, TE properties of (1-x)LaCoO3/(x)La0.7Sr0.3CoO3 (0.00 \leq x \leq 0.05) composite is discussed. The structural analysis confirms individual phases in the composite, which is further supported by electron microscopy analysis. The x-ray photoelectron analysis indicates that oxygen vacancies (VO) are present in the parent LaCoO3 system and increase with the addition of La0.7Sr0.3CoO3 (LSCO) in the composite. The increase in VO raises the degenerate states of cobalt and hence improves S in the composites. Temperature variation in S and {\sigma} are consistent with the spin-state transition and shows the correlation between these two parameters. The reduction in {\kappa} and {\sigma} with the addition of ball-milled La0.7Sr0.3CoO3 in the composite is attributed to the enhanced phonon-phonon and charge carrier scattering, respectively. A synergistic effect of enhanced S and reduced \kappa} result in five times improvement in zT of the composite compared to the parent LaCoO3 system at 800 K. This approach also improves the operating temperature for LaCoO3 based systems.