Moir\'e, Euler, and self-similarity -- the lattice parameters of twisted hexagonal crystals

TL;DR

This paper introduces a real-space method to calculate Moiré lattice parameters in twisted hexagonal 2D crystals, revealing complex, angle-dependent patterns and insights into quasicrystalline structures at specific rotations.

Contribution

It presents a novel real-space approach for analyzing Moiré lattice parameters, including discrete solutions and complex angle dependencies, advancing understanding of twisted 2D crystal superstructures.

Findings

Moiré lattice parameters follow a hyperbolic angle dependence.

Discrete solutions arise due to lattice commensurability.

Special case at 30° rotation leads to dodecagonal quasicrystals.

Abstract

A real-space approach for the calculation of the Moir\'e lattice parameters for superstructures formed by a set of rotated hexagonal 2D crystals such as graphene or transition-metal dichalcogenides, is presented. Apparent Moir\'e lattices continuously form for all rotation angles, and their lattice parameter in a good approximation follows a hyperbolical angle dependence. Moir\'e crystals, i.e. Moir\'e lattices decorated with a basis, require more crucial assessment of the commensurabilities and lead to discrete solutions and a non-continuous angle dependence of the Moir\'e-crystal lattice parameter. In particular, this lattice parameter critically depends on the rotation angle, and continuous variation of the angle can lead to apparently erratic changes of the lattice parameter. The solutions form a highly complex pattern, which reflects number-theoretical relations between formation parameters of the Moir\'e crystal. The analysis also provides insight into the special case of a 30{\deg} rotation of the constituting lattices, for which a dodecagonal quasicrystalline structure forms.