Constraints of the formation and abundances of methyl carbamate, a glycine isomer, in hot corinos

TL;DR

This study investigates the formation and abundance constraints of methyl carbamate, a glycine isomer, in hot corino environments, combining astrochemical modeling with analysis of ALMA data to guide future detections.

Contribution

First astrochemical modeling of methyl carbamate formation in hot corino conditions, with observational analysis providing upper limits and potential spectral features.

Findings

Chemical models align with observational upper limits.

Three spectral features possibly related to methyl carbamate identified.

Future telescopes may confirm methyl carbamate presence in hot corinos.

Abstract

Methyl carbamate CH$_3$OC(O)NH$_2$ is an isomer of glycine. Quantum chemical analyses show that methyl carbamate is more stable isomer than glycine. Because of this, there could be a higher chance for methyl carbamte to exist in the interstellar medium as compared to glycine. Despite immense searches, till now glycine has not been detected in the ISM, therefore it is worthwhile to search its isomer methyl carbamate. In this paper, we present the constraints of methyl carbamate formation under the interstellar conditions. Large complex organic molecules are favorably produced in hot-corino environments of low mass protostars. We for the first time carried out astrochemical modeling focusing on the formation of methyl carbamate in physical conditions similar to hot-corino objects. Consequently, we examined ALMA archival data for existing spectral line observations toward hot corinos NGC1333 IRAS 4A2 and IRAS 16293B. Within the common spectral range towards these sources, we found three features are possibly related to the spectral transitions of methyl carbamate and consequently estimate the upper limit of column densities. Results of chemical modeling are consistent with the observational upper limit of estimated column density/abundance toward the sources. This may hint the validation of the proposed formation mechanism. Future observations using telescope like ngVLA may confirm the presence of MC toward the hot corinos.