Steering alkyne homocoupling with on-surface synthesized catalysts
Mohammed S. G. Mohammed, Luciano Colazzo, Aurelio Gallardo, Jos\'e A., Pomposo, Pavel Jel\'inek, Dimas G. de Oteyza
TL;DR
This paper presents a multi-step on-surface synthesis approach where metal-organic complexes are created and used as catalysts to control alkyne homocoupling reactions, with analysis of resulting electronic properties.
Contribution
It introduces a novel on-surface synthesis method for catalysts that direct alkyne coupling, along with electronic property analysis of the products.
Findings
Successful synthesis of metal-organic complexes on surfaces
Effective steering of alkyne homocoupling reactions
Comparison of electronic properties of coupling motifs
Abstract
We report a multi-step on-surface synthesis strategy. The first step consists in the surface-supported synthesis of metal-organic complexes, which are subsequently used as catalysts to steer on-surface alkyne coupling reactions. In addition, we analyze and compare the electronic properties of the different coupling motifs obtained.
Peer Reviews
No public reviews on file for this paper yet. If you reviewed it on a platform where reviews are public (OpenReview, ICLR, NeurIPS, ICML), you can paste yours below so the community can read it here.
Videos
No videos yet. Explain this paper in a talk, walkthrough, or lecture? Add one.