Temperature- and Polarization- Dependent Optical Properties of Single Si2Te3 Nanoplates

TL;DR

This study combines experimental and computational methods to investigate the temperature- and polarization-dependent optical properties of single Si2Te3 nanoplates, revealing anisotropic absorption and vibrational modes relevant for optoelectronic applications.

Contribution

It provides new insights into the anisotropic optical and vibrational properties of Si2Te3 nanoplates, supported by both experimental measurements and theoretical calculations.

Findings

Si2Te3 nanoplates exhibit a direct band gap of 2.394 eV at 7 K.

Polarized reflection shows anisotropic absorption due to silicon dimer orientation.

Vibrational modes match density functional perturbation theory predictions.

Abstract

We report a combined experimental and computational study of the optical properties of individual silicon telluride (Si2Te3) nanoplates. The p-type semiconductor Si2Te3 has a unique layered crystal structure with hexagonal closed-packed Te sublattices and Si-Si dimers occupying octahedral intercalation sites. The orientation of the silicon dimers leads to unique optical and electronic properties. Two-dimensional Si2Te3 nanoplates with thicknesses of hundreds of nanometers and lateral sizes of tens of micrometers are synthesized by a chemical vapor deposition technique. At temperatures below 150 K, the Si2Te3 nanoplates exhibit a direct band structure with a band gap energy of 2.394 eV at 7 K and an estimated free exciton binding energy of 150 meV. Polarized reflection measurements at different temperatures show anisotropy in the absorption coefficient due to an anisotropic orientation of the silicon dimers, which is in excellent agreement with theoretical calculations of the dielectric functions. Polarized Raman measurements of single Si2Te3 nanoplates at different temperatures reveal various vibrational modes, which agree with density functional perturbation theory calculations. The unique structural and optical properties of nanostructured Si2Te3 hold great potential applications in optoelectronics and chemical sensing.