Revisiting the Sulfur-Water Chemical System in the Middle Atmosphere of Venus

TL;DR

This study uses a one-dimensional model to analyze sulfur-water chemistry in Venus's middle atmosphere, explaining observed anti-correlations of SO2 and H2O through chemical interactions and mixing ratio variations.

Contribution

It demonstrates that sulfur-water chemistry regimes are continuous without bifurcations and highlights the influence of cloud top mixing ratios on atmospheric composition.

Findings

SO2 and H2O ratios depend on cloud top mixing ratios.

No abrupt regime transitions or bifurcations occur.

Variations are influenced by lower atmospheric processes.

Abstract

Sulfur-water chemistry plays an important role in the middle atmosphere of Venus. Ground based observations have found that simultaneously observed SO2 and H2O at ~64 km vary with time and are temporally anti-correlated. To understand these observations, we explore the sulfur-water chemical system using a one-dimensional chemistry-diffusion model. We find that SO2 and H2O mixing ratios above the clouds are highly dependent on mixing ratios of the two species at the middle cloud top (58 km). The behavior of sulfur-water chemical system can be classified into three regimes but there is no abrupt transition among these regimes. In particular, there is no bifurcation behavior as previously claimed. We also find that the SO2 self-shielding effect causes H2O above the clouds to respond to the middle cloud top in a non-monotonic fashion. Through comparison with observations, we find that mixing ratio variations at the middle cloud top can explain the observed variability of SO2 and H2O. The sulfur-water chemistry in the middle atmosphere is responsible for the H2O-SO2 anti-correlation at 64 km. Eddy transport change alone cannot explain the variations of both species. These results imply that variations of species abundance in the middle atmosphere are significantly influenced by the lower atmospheric processes. Continued ground-based measurements of the co-evolution of SO2 and H2O above the clouds and new spacecraft missions will be crucial for uncover the complicated processes underlying the interaction among the lower atmosphere, the clouds and the middle atmosphere of Venus.