Tribocorrosion under galvanic interaction of Ti6Al4V and NiCr implant alloys

TL;DR

This study investigates how galvanic interactions between Ti6Al4V and NiCr dental implant alloys influence tribocorrosion behavior in fluoride-rich oral environments, revealing increased resistance due to electrochemical potential shifts.

Contribution

It provides new insights into the galvanic effects on tribocorrosion of dental alloys, highlighting the protective role of NiCr in Ti6Al4V under simulated oral conditions.

Findings

Galvanic interaction increases Ti6Al4V tribocorrosion resistance.

Coupling Ti6Al4V with NiCr reduces electrochemical potential decay.

Electrochemical shift from active to passive enhances durability.

Abstract

Micromovements that occur in the joint between dental prostheses and implants can lead to wear-induced degradation. This process can be enhanced by corrosion in the oral environment influenced by the presence of solutions containing fluoride. Moreover, the eventual galvanic interactions between NiCr and Ti alloys can accelerate the wear-corrosion process. In this work, the tribocorrosion process of Ti6Al4V and NiCr alloys used in dental implant rehabilitations immersed in fluoride solutions at different pH values was investigated. The galvanic interaction effect between the alloys was also assessed. Tribocorrosion tests in corrosive media were performed with isolated Ti6Al4V and NiCr alloys, followed by testing with both alloys in contact. The media selected were based on fluoride concentrations and pH values that are possible to be found in oral environments. Analysis of the surfaces after the tribocorrosion tests was carried out using confocal laser microscopy. The wear profile and volume losses were determined by confocal measurements. It was concluded that the galvanic interaction between the alloys increased the tribocorrosion resistance of Ti6Al4V, compared with that of the isolated Ti6Al4V alloy. Ti6Al4V coupled with NiCr reduced the electrochemical potential decay during sliding. The increased resistance was explained by the electrochemical shift of the Ti6Al4V potential from active dissolution to the passive domain.