Adsorbates as a charge-carrier reservoir for electrostatic carrier doping to graphene

TL;DR

This paper investigates how adsorbates like oxygen and water act as charge-carrier reservoirs in electrostatic doping of graphene, revealing that they dominate over multilayer graphene in controlling carrier concentration.

Contribution

It demonstrates that adsorbates serve as the primary charge-carrier reservoir in electrostatic doping of graphene with a self-assembled monolayer.

Findings

Adsorbates like oxygen and water are the main reservoirs for charge carriers.

Multilayer graphene does not significantly contribute as a reservoir.

Carrier doping levels are consistent between isolated and multilayer graphene regions.

Abstract

A charge-carrier reservoir is necessary for electrostatic control of the carrier concentration in a solid. The source/drain electrodes serve as carrier reservoirs in a field-effect transistor, but it is still unknown what serves as a reservoir in a technique based on a polar self-assembled monolayer formed underneath a solid to be controlled. Here, the carrier-doping level of isolated single-layer graphene was found to be the same as that of the single-layer part in a flake containing multilayer graphene, indicating that the multilayer part is not a dominant carrier reservoir but adsorbates like oxygen and water serve as a dominant reservoir.