Simple approach to model the strength of solid-solution high entropy alloys in Co-Cr-Fe-Mn-Ni system

TL;DR

This paper introduces a simple polynomial fitting method to model the strength of Co-Cr-Fe-Mn-Ni high entropy alloys, analyzing how composition and parameters like enthalpy of mixing affect hardness.

Contribution

A novel polynomial modeling approach for predicting the strength of high entropy alloys based on experimental data and compositional parameters.

Findings

Strength decreases with increasing Fe content.

Hardness increases with decreasing enthalpy of mixing.

Hardness increases with higher valence electron concentration.

Abstract

A simple fitting approach is introduced for modeling the strength (hardness) of quaternary and quinary face-centered cubic (fcc) solid solution high entropy alloys (HEAs) in Co-Cr-Fe-Mn-Ni system. It is proposed that the strength of solid solution HEAs could be modeled by a polynomial equation where experimental data are used for finding the coefficients of polynomial. It is observed that the proposed polynomial could model the strength of solid solution HEAs very well. Effects of constituent elements on the hardness of quinary Co-Cr-Fe-Mn-Ni alloys are investigated; the results indicate that the strength of alloys decreases with increasing the Fe content. The softening effect of Fe is explained by considering its effect on decreasing the shear modulus of alloys. Furthermore, the effects of parameters enthalpy of mixing and valence electron concentration on the strength of HEAs are investigated. The results show that the enthalpy of mixing has a noticeable effect on the hardness of quinary Co-Cr-Fe-Mn-Ni alloys and the strength increases with decreasing the enthalpy of mixing. Furthermore, the results show that hardness of quinary Co-Cr-Fe-Mn-Ni alloys increases with increasing the parameter valence electron concentration.