Enhanced Valley Zeeman Splitting in Fe-Doped Monolayer MoS2

TL;DR

This study demonstrates room-temperature control of valley Zeeman splitting in Fe-doped MoS2 monolayers, achieving significant enhancement through magnetic doping, which is promising for valleytronic applications.

Contribution

It provides experimental evidence and theoretical understanding of enhanced valley Zeeman splitting at room temperature via Fe doping in MoS2 monolayers.

Findings

Valley Zeeman splitting observed at 300 K with g = -6.4

Effective g factor increased to -20.7 with higher Fe doping

Enhanced splitting attributed to exchange interaction between Fe moments and MoS2

Abstract

The Zeeman effect offers unique opportunities for magnetic manipulation of the spin degree of freedom (DOF). Recently, valley Zeeman splitting, referring to the lifting of valley degeneracy, has been demonstrated in two-dimensional transition metal dichalcogenides (TMDs) at liquid helium temperature. However, to realize the practical applications of valley pseudospins, the valley DOF must be controllable by a magnetic field at room temperature, which remains a significant challenge. Magnetic doping in TMDs can enhance the Zeeman splitting, however, to achieve this experimentally is not easy. Here, we report unambiguous magnetic manipulation of valley Zeeman splitting at 300 K (g = -6.4) and 10 K (g = -11) in a CVD-grown Fe-doped MoS2 monolayer; the effective g factor can be tuned to -20.7 by increasing the Fe dopant concentration, which represents an approximately fivefold enhancement as compared to undoped MoS2. Our measurements and calculations reveal that the enhanced splitting and geff factors are due to the Heisenberg exchange interaction of the localized magnetic moments (Fe 3d electrons) with MoS2 through the d-orbital hybridization.