Structural defects in MBE-grown CdTe-based heterojunctions for photovoltaic applications

TL;DR

This study investigates structural defects in MBE-grown CdTe-based heterojunctions using TEM, DLTS, and X-ray diffractometry, revealing dislocation networks and deep-level traps that impact photovoltaic efficiency.

Contribution

It provides detailed characterization of defects and their electronic states in MBE-grown CdTe heterojunctions, linking structural imperfections to photovoltaic performance.

Findings

Dislocation networks are prevalent at lattice-mismatched interfaces.

Deep-level traps are associated with dislocations and vacancies.

Defects likely reduce carrier lifetime and solar cell efficiency.

Abstract

Structural defects in the p-ZnTe/i-CdTe/n-CdTe single-crystalline heterojunctions designed for photovoltaic applications have been investigated by transmission electron microscopy (TEM) and deep-level transient spectroscopy (DLTS). Lattice parameters and misfit strain in the undoped CdTe absorber layers of the heterojunctions, grown by the molecular-beam epitaxy technique on two different substrates, GaAs and CdTe, have been determined with high-resolution X-ray diffractometry. A dense network of misfit dislocations at the lattice-mismatched CdTe/GaAs and ZnTe/CdTe interfaces and numerous threading dislocations and stacking faults have been shown by the cross-sectional TEM imaging of the heterojunctions. The DLTS measurements revealed five deep-level traps in the heterojunctions grown on the GaAs substrates and only three of them in the heterojunctions grown on CdTe. One of the traps, showing the exponential capture kinetics of charge carriers, has been identified as associated with the double acceptor level of Cd vacancies in the CdTe absorber layers. All the other traps have been attributed to the electronic states of extended defects, presumably dislocations, on the grounds of their logarithmic capture kinetics. Two of these traps, displaying the largest values of their capture cross-section and the properties characteristic of bandlike electronic states, have been ascribed to the core states of dislocations. It is argued that they are most likely responsible for decreased lifetime of photo-excited carriers resulting in a low energy conversion efficiency of solar cells based on similarly grown heterojunctions.