Revealing The CO X-factor In Dark Molecular Gas through Sensitive ALMA Absorption Observations
Gan Luo, Di Li, Ningyu Tang, J. R. Dawson, John M. Dickey, L., Bronfman, Sheng-Li Qin, Steven J. Gibson, Richard Plambeck, Ricardo Finger,, Anne Green, Diego Mardones, Bon-Chul Koo, Nadia Lo

TL;DR
This study uses sensitive ALMA absorption observations to investigate the properties of CO and HCO+ in diffuse molecular gas, revealing that HCO+ is a more reliable tracer of H2 than CO in such environments.
Contribution
The paper provides the first direct measurements of excitation temperatures and the CO X-factor in diffuse molecular gas using sensitive absorption lines, highlighting HCO+ as a superior tracer of H2.
Findings
CO detected in very low extinction regions (A_v<0.32 mag)
HCO+ shows a strong correlation with H2 (P ~ 0.93)
Derived CO X-factor is about 6 times higher than the Milky Way average
Abstract
Carbon-bearing molecules, particularly CO, have been widely used as tracers of molecular gas in the interstellar medium (ISM). In this work, we aim to study the properties of molecules in diffuse, cold environments, where CO tends to be under-abundant and/or sub-thermally excited. We performed one of the most sensitive (down to and ) sub-millimeter molecular absorption line observations towards 13 continuum sources with the ALMA. CO absorption was detected in diffuse ISM down to and \hcop was down to , where atomic gas and dark molecular gas (DMG) starts to dominate. Multiple transitions measured in absorption toward 3C454.3 allow for a direct determination of excitation temperatures of 4.1\,K and 2.7\,K, for CO and for \hcop, respectively,…
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