Confronting Interatomic Force Measurements

TL;DR

This paper introduces a new mathematical method for interatomic force measurements using atomic force microscopy, enabling more accurate force law evaluations within feasible oscillation amplitudes, improving material characterization.

Contribution

A novel mathematical conversion approach that maintains oscillation amplitudes within practical limits, enhancing the reliability of interatomic force measurements.

Findings

New conversion principle preserves feasible oscillation amplitudes.

Reduces deviation from actual interatomic force laws.

Improves accuracy of material property evaluation.

Abstract

The quantitative interatomic force measurements open a new pathway to materials characterization, surface science, and chemistry by elucidating the force between 'two' interacting atoms as a function of their separation. Atomic force microscope is the ideal platform to gauge interatomic forces between the tip and the sample. For such quantitative measurements, either the oscillation frequency or the oscillation amplitude and the phase of a vibrating cantilever are recorded as a function of the tip-sample separation. These experimental measures are subsequently converted into the interatomic force laws. Recently, it has been shown that the most commonly applied mathematical conversion techniques may suffer a significant deviation from the actual force laws. To avoid assessment of unphysical interatomic forces, either the use of very small (i.e., a few picometers) or very large oscillation amplitudes (i.e., a few nanometers) has been proposed. However, the use of marginal oscillation amplitudes gives rise to another problem as it lacks the feasibility due to the adverse signal to noise ratios. Here we show a new mathematical conversion principle that confronts interatomic force measurements while preserving the oscillation amplitude within the experimentally achievable and favorable limits, i.e. tens of picometers. We anticipate that our findings will be the nucleus of reliable evaluation of material properties with a more accurate measurement of interatomic force laws.