CaPtAs: a new noncentrosymmetric superconductor

TL;DR

This paper reports the discovery and characterization of CaPtAs, a new noncentrosymmetric superconductor with unconventional properties, including possible p-wave pairing and significant anisotropy, supported by experimental and theoretical analysis.

Contribution

The study introduces CaPtAs as a novel noncentrosymmetric superconductor with unique structural and electronic features, expanding understanding of unconventional superconductivity.

Findings

Superconducting transition temperature $T_c$ = 1.47 K.

Evidence for p-wave-like behavior in specific heat.

Large anisotropy in upper critical field.

Abstract

We report the discovery of a new noncentrosymmetric superconductor CaPtAs. It crystallizes in a tetragonal structure (space group $I4_1md$, No.109), featuring three dimensional honeycomb networks of Pt-As and a much elongated $c$-axis ($a = b = 4.18 $ \AA, and $c = 43.70 $ \AA). The superconductivity of CaPtAs with $T_c$ = 1.47 K was characterized by means of electrical resistivity, specific heat, and ac magnetic susceptibility. The electronic specific heat $C_\mathrm{e}(T)/T$ shows evidence for a deviation from the behavior of a conventional BCS superconductor, and can be reasonably fitted by a $p$-wave model. The upper critical field $\mu_0H_{c2}$ of CaPtAs exhibits a relatively large anisotropy, with an in-plane value of around 204 mT and an out-of-plane value of 148 mT. Density functional theory calculations indicate that the Pt-5$d$ and As-4$p$ orbitals mainly contribute to the density of states near the Fermi level, showing that the Pt-As honeycomb networks may significantly influence the superconducting properties.