Analysis of the C$_2$ (d$^3\Pi_g$-a$^3\Pi_u$) Swan bands as a thermometric probe in CO$_2$ microwave plasmas

TL;DR

This study evaluates the use of C$_2$ Swan bands as a reliable optical thermometric probe in high-pressure CO$_2$ microwave plasmas, confirming a consistent gas temperature around 6000 K across various conditions.

Contribution

It demonstrates that C$_2$ Swan bands can accurately measure gas temperature in CO$_2$ microwave plasmas using state-by-state fitting and validates this method with additional CN band measurements.

Findings

C$_2$ Swan bands provide a consistent temperature estimate of about 6000 K.

Rotational temperature of C$_2$ correlates with the plasma's gas temperature.

The study offers a spectroscopic database for C$_2$ Swan bands for future research.

Abstract

The optical emission spectra of high pressure CO$_2$ microwave plasmas are usually dominated by the C$_2$ Swan bands. In this paper, the use of the C$_2$ Swan bands for estimating the gas temperature in CO$_2$ microwave plasmas is assessed. State by state fitting is employed to check the correctness of assuming a Boltzmann distribution for the rotational and vibrational distribution functions and, within statistical and systematic uncertainties, the C$_2$ Swan band can be fitted accurately with a single temperature for rotational and vibrational levels. The processes leading to the production of the C$_2$ molecule and particularly its d$^3\Pi_g$ state are briefly reviewed as well as collisional relaxation times of the latter. It is concluded that its rotational temperature can be associated to the gas temperature of the CO$_2$ microwave plasma and the results are moreover cross-checked by adding a small amount of N$_2$ in the discharge and measuring the CN violet band system. The 2.45~GHz plasma source is analyzed in the pressure range 180-925~mbar, for input microwave powers ranging from 0.9 - 3 kW and with gas flow rates of 5-100~L/min. An intense C$_2$ Swan bands emission spectrum can be measured only when the plasma is operated in contracted regime. A unique temperature of about 6000 $\pm$ 500 K is obtained for all investigated conditions. A spectroscopic database is constructed using the recent compilation and calculations by Brooke et al. \cite{BROOKE201311} of the line strengths and molecular constants for the C$_2$ (d$^3\Pi_g$-a$^3\Pi_u$) Swan bands system and made available as Supplementary Material in a format compatible with the open source MassiveOES software.