Synthesis, magnetization and heat capacity of triangular lattice materials NaErSe$_2$ and KErSe$_2$

TL;DR

This study synthesizes and characterizes NaErSe$_2$ and KErSe$_2$, revealing their frustrated magnetic behavior, anisotropy, and potential as quantum spin liquid candidates due to absence of long-range order.

Contribution

It provides the first detailed magnetic and heat capacity analysis of AErSe$_2$ compounds with perfect triangular lattices, highlighting their frustrated and anisotropic magnetic properties.

Findings

No long-range magnetic order detected.

Large magnetic anisotropy observed.

Field-induced transitions suggest quantum spin liquid potential.

Abstract

In this paper we report the synthesis, magnetization and heat capacity of the frustrated magnets \emph{A}ErSe$_2$(\emph{A}=Na,K) which contain perfect triangular lattices of Er$^{3+}$. The magnetization data suggests no long-range magnetic order exists in \emph{A}ErSe$_2$(\emph{A}=Na,K), which is consistent with the heat capacity measurements. Large anisotropy is observed between the magnetization within the \emph{ab} plane and along the \emph{c} axis of both compounds. When the magnetic field is applied along \emph{ab} plane, anomalies are observed at 1.8 $\mu_B$ in NaErSe$_2$ at 0.2 T and 2.1 $\mu_B$ in KErSe$_2$ at 0.18 T. Unlike NaErSe$_2$, a plateau-like field-induced metamagnetic transition is observed for H$\|$\emph{c} below 1 K in KErSe$_2$. Two broad peaks are observed in the heat capacity below 10 K indicating possible crystal electric field(CEF) effects and magnetic entropy released under different magnetic fields. All results indicate that \emph{A}ErSe$_2$ are strongly anisotropic, frustrated magnets with field-induced transition at low temperature. The lack of signatures for long-range magnetic order implies that these materials are candidates for hosting a quantum spin liquid ground state.