Externally driven local colloidal ordering induced by a point-like heat source

TL;DR

This study demonstrates how a point-like heat source can induce local phase transitions and diverse colloidal structures, including crystals and amorphous states, through thermophoresis in suspension.

Contribution

It reveals the role of thermophoresis in controlling colloidal phase transitions and structures near a heat source, introducing a new method for studying densification and ordering.

Findings

Solid clusters form around the heat source.

Various structures like FCC crystals and amorphous states are observed.

Cluster sizes are determined by concentration profiles, not thermodynamics.

Abstract

We study here how phase transitions are induced in colloidal suspensions by a point-like heat source, an optically trapped metal oxide particle absorbing light. We find that thermophoresis increases the number density of colloids around the oxide particle, leading to the appearance of solid clusters. Our analysis based on thermophoresis reveals that the solid-fluid interface position is purely determined by the relationship of the particle concentration profile in the fluid state with the volume fraction of the phase transition, and no other effect of thermodynamics is seen in the cluster sizes. In this system, we observe the formation of face-centered cubic crystals, amorphous states, and structures with icosahedral order. This shows a rich possibility of non-trivial orderings under spatially controlled heterogeneous growth in external "semi-soft" potentials that are softer than walls but with substantial variations at the scale of a few particle diameters. Because of the tuneable rate of addition of particles to the clusters, we propose this method could be used to study the complex interplay of densification with local spatial confinement effects, kinetics, and ordering.