Activated diffusiophoresis

TL;DR

This paper explores how localized, diffusive perturbations in a fluid can induce non-equilibrium diffusiophoretic motion of inclusions, enabling controlled transport and work extraction in active and passive matter systems.

Contribution

It introduces a theoretical framework for activated diffusiophoresis, analyzing how local perturbations create controllable inclusion trajectories and potential for energy extraction.

Findings

Activations can induce long-range diffusiophoretic motion.

Time-dependent activation protocols enable stable inclusion transport.

Steady states do not support stable inclusion trapping, similar to Earnshaw's theorem.

Abstract

Perturbations of fluid media can give rise to non-equilibrium dynamics, which may in turn cause motion of immersed inclusions. We consider perturbations ("activations") that are local in space and time, of a fluid density which is conserved, and study the resulting diffusiophoretic phenomena that emerge at a large distance. Specifically, we consider cases where the perturbations propagate diffusively, providing examples from passive and active matter for which this is expected to be the case. Activations can, for instance, be realized by sudden and local changes in interaction potentials of the medium, or by local changes of its activity. Various analytical results are provided for the case of confinement by two parallel walls. We investigate the possibility of extracting work from inclusions which are moving through the activated fluid. Further, we show that a time-dependent density profile, created via suitable activation protocols, allows for conveyance of inclusions along controlled and stable trajectories. In contrast, in states with a steady density, inclusions cannot be held at stable positions, reminiscent of Earnshaw's theorem of electrostatics. We expect these findings to be applicable in a range of experimental systems.