Free energy and entropy for finite temperature quantum field theory under the influence of periodic backgrounds
M. Bordag, J. M. Mu\~noz-Casta\~neda, L. Santamar\'ia-Sanz

TL;DR
This paper calculates thermodynamic quantities like free energy and entropy for a scalar field in periodic potentials, using various frequency representations, and extends previous results to systems with band structure and negative entropy.
Contribution
It introduces a method to compute thermodynamic quantities for scalar fields in periodic backgrounds using imaginary frequency techniques, including systems with band structure.
Findings
Confirmed earlier results on vacuum energy at zero temperature.
Calculated free energy and entropy for specific periodic potentials.
Generalized results to include negative entropy cases.
Abstract
The basic thermodynamic quantities for a non-interacting scalar field in a periodic potential composed of either a one-dimensional chain of Dirac - functions or a specific potential with extended compact support are calculated. First, we consider the representation in terms of real frequencies (or one-particle energies). Then we turn the axis of frequency integration towards the imaginary axis by a finite angle, which allows for easy numerical evaluation, and finally turn completely to the imaginary frequencies and derive the corresponding Matsubara representation, which this way appears also for systems with band structure. In the limit case we confirm earlier results on the vacuum energy. We calculate for the mentioned examples the free energy and the entropy and generalize earlier results on negative entropy.
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