Time-Rate-Transformation framework for targeted assembly of short-range attractive colloidal suspensions

TL;DR

This paper introduces a novel Time-Rate-Transformation framework to better understand and control the targeted assembly of short-range attractive colloidal suspensions by analyzing their complex multiscale aggregation dynamics.

Contribution

It adapts a Time-Rate-Transformation diagram from materials science to colloidal systems, enabling directed assembly under various flow and particle conditions.

Findings

The framework captures multiscale aggregation dynamics.

It allows for targeted control of colloidal assembly.

The approach bridges materials processing and colloid science.

Abstract

The aggregation of attractive colloids has been extensively studied from both theoretical and experimental perspectives as the fraction of solid particles is changed, and the range, type and strength of attractive or repulsive forces between particles varies. The resulting gels consisting of disordered assemblies of attractive colloidal particles, have also been investigated with regards to percolation, phase separation, and the mechanical characteristics of the resulting fractal networks. Despite tremendous progress in our understanding of the gelation process, and the exploration of different routes for arresting the dynamics of attractive colloids, the complex interplay between convective transport processes and many-body effects in such systems has limited our ability to drive the system towards a specific configuration. Here we study a model attractive colloidal system over a wide range of particle characteristics and flow conditions undergoing aggregation far from equilibrium. The complex multiscale dynamics of the system can be understood using a Time-Rate-Transformation diagram adapted from understanding of materials processing in block copolymers, supercooled liquids and much stiffer glassy metals to direct targeted assembly of attractive colloidal particles.