Advanced High-Performance Large Diameter Cs2HfCl6 (CHC) and Mixed Halides Scintillator

TL;DR

This study successfully grew and evaluated large diameter Cs2HfCl6 and mixed halide Cs2HfCl4Br2 scintillator crystals, demonstrating high energy resolution and promising optical properties for radiation detection applications.

Contribution

It presents the first successful growth and comprehensive performance evaluation of large diameter Cs2HfCl6 and Cs2HfCl4Br2 scintillator crystals using the vertical Bridgman method.

Findings

Achieved 3.5% and 3.7% energy resolution at 662 keV for CHC and CHCB.

Produced transparent, crack-free single crystals of 1-inch diameter.

Demonstrated comparable performance to smaller crystals in optical and scintillation properties.

Abstract

This paper reports on successful growth and performance evaluation of two large diameter Cs2HfCl6 (CHC) and Cs2HfCl4Br2 (CHCB), both recently developed scintillator crystals. The discovery of Cs2HfCl6 (CHC) as a scintillator has lately generated much interest in this material and its family, which belongs to the K2PtCl6 cubic crystal structure. CHC is an intrinsic scintillator that is non-hygroscopic, has no self-radioactivity, provides excellent energy resolution, and has excellent non-proportionality. CHC has a moderate density of 3.9 g/cm3 and an effective atomic number of 58. Reported in this paper are transparent crack-free single crystal CHC and CHCB boules of one inch in diameter, both grown using the vertical Bridgman method. Samples retrieved from the boules, sized 23mm dia. x 30mm and 23mm dia. x 26mm, respectively, are characterized for their optical and scintillation properties. Energy resolutions of 3.5% and 3.7% (FWHM) at 662 keV, respectively, are reported. Results comparable to previously reported results for smaller crystals have been obtained. Studies on light yield, decay time, non-proportionality, as well as detector characterization are also reported.