A self-assembled two-dimensional thermo-functional material for radiative cooling

TL;DR

This paper introduces a simple, inexpensive 2D silica microsphere coating that passively cools objects by radiative heat loss through the infrared atmospheric window, significantly reducing temperatures of electronic devices during daytime.

Contribution

It presents a novel self-assembled 2D silica microsphere structure that enhances radiative cooling efficiency for practical thermal management applications.

Findings

Lowered silicon wafer temperature by 14K during daytime

Achieved cooling power density up to 350 W/m2 under sunlight

Demonstrated effective passive cooling using a simple, scalable material

Abstract

The regulation of temperature at the macro and microscale is a major energy-consuming process of humankind. Modern cooling systems account for 15% of the global energy consumption and are responsible for 10% of greenhouse gas emissions. Due to global warming, a ten-fold growth in the demand of cooling technologies is expected in the next 30 years, thus linking global warming and cooling needs through a worrying negative feedback loop. Here, we propose an inexpensive solution to this global challenge based on a single-layer of silica microspheres self-assembled on a soda-lime glass substrate. This two-dimensional (2D) crystal acts as a visibly translucent thermal blackbody for above-ambient daytime radiative cooling and can be used to passively improve the thermal performance of devices that undergo critical heating during operation. The temperature of a crystalline silicon wafer was found to be 14K lower during daytime when covered with our thermal emitter, reaching an average temperature difference of 19K when the structure was backed with a silver layer. In comparison, the soda-lime glass used as a reference in our measurements lowered the temperature of the silicon wafer by just 5 K. The cooling power density of this rather simple radiative cooler under direct sunlight was found to be up to 350 W/m2 when applied to hot surfaces with relative temperatures of 50 K above the ambient. This is crucial to radiatively cool down electronic devices, such as solar cells, where an increase in temperature has drastic effects on performance. Our 2D thermo-functional material includes a single layer of spheres emitting long-wave radiation through the infrared atmospheric window and over a broad wavelength ange, thus providing effective radiative cooling using the outer space as a heat sink at 3 K.