Electronic and magnetic properties of perovskite selenite and tellurite compounds: CoSeO$_3$, NiSeO$_3$, CoTeO$_3$ and NiTeO$_3$

TL;DR

This study uses first principles calculations to explore the electronic and magnetic properties of Co and Ni selenite and tellurite perovskite compounds, revealing their insulating antiferromagnetic nature and Mott insulator characteristics.

Contribution

It provides new insights into the electronic and magnetic behaviors of these rare perovskite compounds, highlighting the role of Jahn-Teller distortions and crystal field effects.

Findings

All compounds are predicted to be insulating G-type antiferromagnets.

Significant differences in exchange anisotropy are linked to Jahn-Teller distortions.

These compounds exhibit characteristics of Mott insulators, even at standard DFT level.

Abstract

Selenium and tellurium are among the few elements that form $AB$O$_3$ perovskite structures with a four valent ion in the $A$ site. This leads to highly distorted structures and unusual magnetic behavior. Here we investigate the Co and Ni selenite and tellurite compounds, CoSeO$_3$, CoTeO$_3$, NiSeO$_3$ and NiTeO$_3$ using first principles calculations. We find an interplay of crystal field and Jahn-Teller distortions that underpin the electronic and magnetic properties. While all compounds are predicted to show an insulating G-type antiferromagnetic ground state, there is a considerable difference in the anisotropy of the exchange interactions between the Ni and Co compounds. This is related to the Jahn-Teller distortion. Finally, we observe that these four compounds show characteristics generally associated with Mott insulators, even when described at the level of standard density functional theory. These are then dense bulk band or Slater, Mott-type insulators.