Unfolding femtoscale ionic movement in CuO through polarized Raman spectroscopy

TL;DR

This study uses polarized Raman spectroscopy to directly detect femtometer-scale ionic displacements in CuO, supporting theoretical models of its multiferroic behavior and demonstrating a novel method for observing tiny ionic shifts.

Contribution

It provides the first experimental validation of ionic displacement along the b-axis in CuO using polarized Raman scattering at femto-scale resolution.

Findings

Validated theoretical ionic displacement predictions in CuO

Demonstrated polarized Raman spectroscopy as a tool for femto-scale detection

Contributed to understanding high-temperature multiferroic materials

Abstract

Recently, CuO has been proposed as a potential multiferroic material with high transition temperature. Competing models based on spin current and ionic displacements are invoked to explain ferroelectricity in CuO. The theoretical model predicting ionic displacement suggested that the shift in ions is essentially along b-axis with very small amplitude (~10-5 {\AA}). Experimentally detecting displacements of such a small amplitude in a particular direction is extremely challenging. Through our detailed polarized Raman spectroscopy study on epitaxial film of CuO, we have validated the theoretical study and provided direct evidence of displacement along the b-axis. Our study provides important contribution in the high temperature multiferroic compounds and showed for the first time, the use of the polarized Raman scattering in detecting ionic displacements at the femto-scale.