Absorption and Plasmon Resonance of Bi-Metallic Core-Shell Nanoparticles on a Dielectric Substrate Near an External Tip

TL;DR

This study investigates the absorption and plasmon resonance properties of metallic core-shell nanoparticles on a dielectric substrate, revealing how size, environment, and external tips influence their optical responses for various applications.

Contribution

It introduces a numerical approach to analyze core-shell nanoparticle plasmonics near substrates and tips, highlighting the effects of size, environment, and polarization on absorption and resonance.

Findings

Significant absorption enhancement with redshift in LSPR for Ag-Au core-shell NPs.

Shell dominance over plasmon response at small core volumes.

Polarization effects cause switching in absorption enhancement at different wavelengths.

Abstract

Absorption efficiency profiles and localized surface plasmon resonance (LSPR) wavelengths are reported for metallic core-shell nanoparticles (NPs) placed over a BK7 glass substrate. A numerical study is performed with the vectorized version of the discrete dipole approximation with surface interactions (DDA-SI-v). Gold (Au) and silver (Ag) metallic components are used for the simulations of two different core-shell structures. Absorption enhancement and the hybrid modes of plasmon resonances of the core-shell structures are compared by using a measure that defines a size configuration. It is observed that a small volume fraction of the core sizes results in shell domination over the plasmon response. An additional study is conducted to discern the sensitivity of the refractive index of nanoparticles in different surrounding environments. With a selected core-shell size configuration of Ag-Au pairs, a significant absorption enhancement with a redshift of LSPR wavelength is observed for both Ag core-Au shell and Au core-Ag shell NPs. The absorption behavior of the bare metallic NPs and selected core-shell pairs in proximity to an external probe is also analyzed. The gallium phosphide (GaP) and silicon (Si) AFM tip usage are investigated with transverse electric (TE) and transverse magnetic (TM) wave polarizations. It is observed that the dominance of light polarization on the absorption enhancement of the NPs switches at different wavelengths, where the dielectric transition for tip materials occurs. These findings show the possible targeted uses of metallic core-shell nanoparticles in several areas such as nanomanufacturing, localized heating, bio-sensing, and material detection applications.