Sulfur-bearing molecules in Orion KL

TL;DR

This study maps sulfur-bearing molecules in Orion KL, revealing distinct spatial distributions and abundance variations of carbon-sulfur and carbon-free species, linked to temperature and shock processes.

Contribution

It provides the first detailed spatial and abundance analysis of multiple sulfur-bearing molecules in Orion KL using combined ALMA and IRAM-30m data, highlighting their different behaviors.

Findings

Carbon-sulfur compounds are concentrated around continuum peaks.

Carbon-free S-bearing species are more extended and broader in linewidths.

Abundances of certain molecules increase with temperature, indicating chemical evolution.

Abstract

We present an observational study of the sulfur (S)-bearing species towards Orion KL at 1.3 mm by combining ALMA and IRAM-30\,m single-dish data. At a linear resolution of $\sim$800 au and a velocity resolution of 1 $\mathrm{km\, s^{-1}\, }$, we have identified 79 molecular lines from 6 S-bearing species. In these S-bearing species, we found a clear dichotomy between carbon-sulfur compounds and carbon-free S-bearing species in various characteristics, e.g., line profiles, spatial morphology, and molecular abundances with respect to $\rm H_2$. Lines from the carbon-sulfur compounds (i.e., OCS, $^{13}$CS, H$_2$CS) exhibit spatial distributions concentrated around the continuum peaks and extended to the south ridge. The full width at half maximum (FWHM) linewidth of these molecular lines is in the range of 2 $\sim$ 11 $\mathrm{km\, s^{-1}\, }$. The molecular abundances of OCS and H$_2$CS decrease slightly from the cold ($\sim$68 K) to the hot ($\sim$176 K) regions. In contrast, lines from the carbon-free S-bearing species (i.e., SO$_2$, $^{34}$SO, H$_2$S) are spatially more extended to the northeast of mm4, exhibiting broader FWHM linewidths (15 $\sim$ 26 $\mathrm{km\, s^{-1}\, }$). The molecular abundances of carbon-free S-bearing species increase by over an order of magnitude as the temperature increase from 50 K to 100 K. In particular, $\mathrm{^{34}SO/^{34}SO_2}$ and $\mathrm{OCS/SO_2}$ are enhanced from the warmer regions ($>$100 K) to the colder regions ($\sim$50 K). Such enhancements are consistent with the transformation of SO$_2$ at warmer regions and the influence of shocks.