Continuous-wave coherent Raman spectroscopy for improving the accuracy of Raman shifts

TL;DR

This paper introduces a low-cost continuous-wave stimulated Raman spectroscopy method that significantly improves the accuracy of Raman shift measurements, achieving uncertainties below 0.1 cm$^{-1}$ for calibration purposes.

Contribution

The authors demonstrate a simple, cost-effective cwSRS and cwCARS setup that enhances Raman shift accuracy and provides a new standard for spectrometer calibration.

Findings

Achieved Raman shift uncertainty below 0.1 cm$^{-1}$

Provided an order of magnitude improvement over existing standards

Validated the method on polystyrene samples

Abstract

Raman spectroscopy is an appealing technique that probes molecular vibrations in a wide variety of materials with virtually no sample preparation. However, accurate and reliable Raman measurements are still a challenge and require more robust and practical calibration methods. We demonstrate the implementation of a simple low-cost continuous-wave stimulated Raman spectroscopy scheme for accurate and high-resolution spectroscopy. We perform shot noise limited continuous-wave stimulated Raman scattering (cwSRS) as well as continuous-wave coherent anti-Stokes Raman scattering (cwCARS) on polystyrene samples. Our method enables accurate determination of Raman shifts with an uncertainty below 0.1 cm$^{-1}$. The setup is used for the characterization of reference materials required for the calibration of Raman spectrometers. Compared with existing standards, we provide an order of magnitude improvement of the uncertainty of Raman energy shifts in a polystyrene reference material.