Chemical Abundances in a Turbulent Medium -- H$_2$, OH$^+$, H$_2$O$^+$, ArH$^+$

TL;DR

This study uses MHD simulations and chemical modeling to explore how turbulence influences molecular ion abundances in the interstellar medium, matching observations and revealing the impact of turbulence parameters.

Contribution

It introduces a detailed modeling approach linking turbulence characteristics to molecular ion abundances, explaining observed abundance scatter and ratios in the diffuse ISM.

Findings

Higher Mach numbers increase abundance dispersion.

Large decorrelation scales lead to more coherent density fluctuations.

Supersonic turbulence explains high ArH$^+$ to OH$^+$ ratios.

Abstract

Supersonic turbulence results in strong density fluctuations in the interstellar medium (ISM), which have a profound effect on the chemical structure. Particularly useful probes of the diffuse ISM are the ArH$^+$, OH$^+$, H$_2$O$^+$ molecular ions, which are highly sensitive to fluctuations in the density and the H$_2$ abundance. We use isothermal magnetohydrodynamic (MHD) simulations of various sonic Mach numbers, $\mathcal{M}_s$, and density decorrelation scales, $y_{\rm dec}$, to model the turbulent density field. We post-process the simulations with chemical models and obtain the probability density functions (PDFs) for the H$_2$, ArH$^+$, OH$^+$ and H$_2$O$^+$ abundances. We find that the PDF dispersions increases with increasing $\mathcal{M}_s$ and $y_{\rm dec}$, as the magnitude of the density fluctuations increases, and as they become more coherent. Turbulence also affects the median abundances: when $\mathcal{M}_s$ and $y_{\rm dec}$ are high, low-density regions with low H$_2$ abundance become prevalent, resulting in an enhancement of ArH$^+$ compared to OH$^+$ and H$_2$O$^+$. We compare our models with Herschel observations. The large scatter in the observed abundances, as well as the high observed ArH$^+$/OH$^+$ and ArH$^+$/H$_2$O$^+$ ratios are naturally reproduced by our supersonic $(\mathcal{M}_s=4.5)$, large decorrelation scale $(y_{\rm dec}=0.8)$ model, supporting a scenario of a large-scale turbulence driving. The abundances also depend on the UV intensity, CR ionization rate, and the cloud column density, and the observed scatter may be influenced by fluctuations in these parameters.