Barium Tagging with Selective, Dry-Functional, Single Molecule Sensitive On-Off Fluorophores for the NEXT Experiment

TL;DR

This paper discusses a novel barium tagging technique using single molecule sensitive fluorophores to detect barium ions in xenon gas, aiming to improve background suppression in neutrinoless double beta decay experiments.

Contribution

It introduces a new dry-state, barium-sensitive fluorescent dye with single ion sensitivity and reports progress towards implementing this in large xenon gas volumes for the NEXT experiment.

Findings

Single barium ions can be resolved via SMFI.

New Ba$^{2+}$-selective dye functions under experimental conditions.

Progress in fluorescence detection devices for in-gas applications.

Abstract

In the search for neutrinoless double beta decay, understanding and reducing backgrounds is crucial for success. An advance that could drive backgrounds to negligible levels would be the ability to efficiently detect the barium daughter in $^{136}$Xe to $^{136}$Ba double beta decay, since no conventional radioactive process can produce barium ions or atoms in xenon at significant rates. In xenon gas, the barium daughter most likely survives as a dication. An approach under development by the NEXT collaboration involves transporting this ion from the active medium onto a coated transparent plane supporting a barium-sensitive fluorescent dye, monitored via fluorescence microscopy. Upon exposure to a barium dication, the dye will begin fluorescing, which, when correlated with the detection of a double electron signal at the anode, would confirm double beta decay.Our results have shown that a single barium ion can be resolved via Single Molecule Fluorescent Imaging (SMFI). The next challenge is a realization of this technique within in a large volume of xenon gas. Significant advances have recently been made: custom barium-tagging molecules that fluoresce strongly in the dry state when exposed to barium have been demonstrated, and devices constructed that can observe fluorescence via in-vacuum or in-gas Total Internal Reflection Fluorescence Microscopy. We present the status of this technique and the outlook for barium tagging with On-Off switchable fluorophores, including new results with a Ba$^{2+}$-selective dye that functions under our desired conditions in the visible region and with single ion sensitivity.