Isotropic charge screening of the anisotropic black phosphorus revealed by potassium adatoms

TL;DR

This paper reveals that despite black phosphorus's inherent anisotropy, its electrostatic charge screening is isotropic, as demonstrated through STM measurements of potassium adatoms, impacting understanding of electron transport.

Contribution

It uncovers the unexpected isotropic charge screening behavior in anisotropic black phosphorus using STM techniques.

Findings

Black phosphorus exhibits isotropic electrostatic screening despite its anisotropic properties.

STM measurements of potassium adatoms reveal isotropic Coulomb fields.

This discovery impacts the understanding of electron scattering in black phosphorus.

Abstract

Black phosphorus has attracted great research interest due to its numerous applications in electronic devices, optoelectronic devices, energy storages and so on. Compared with the majority of two-dimensional materials, black phosphorus possesses a unique property, i.e. the strong in-plane anisotropy. All the properties reported so far, including its effective mass, electron mobility, light absorption, thermal conductivity and so on, have shown great anisotropy in the basal plane. This property renders black phosphorus unique applications not achievable with other two-dimensional materials. In this work, however, we discover a remarkable isotropic behavior in the strongly anisotropic black phosphorus, i.e. its electrostatic screening of point charges. We use the tip-induced band bending of a scanning tunneling microscope to map out the Coulomb field of ionized potassium adatoms on black phosphorus, and reveal its isotropic charge screening. This discovery is important for understanding electron scattering and transport in black phosphorus.