On a thin film model with insoluble surfactant
Gabriele Bruell, Rafael Granero-Belinch\'on

TL;DR
This paper investigates the mathematical properties of a thin film model with insoluble surfactant, proving the existence of solutions and their exponential decay to equilibrium under various physical forces.
Contribution
It establishes the existence of global weak solutions for medium initial data and provides explicit decay rates towards equilibrium in a complex physical setting.
Findings
Existence of global weak solutions for medium initial data.
Exponential decay towards flat equilibrium state.
Explicit decay rate estimates provided.
Abstract
This paper studies the existence and asymptotic behavior of global weak solutions for a thin film equation with insoluble surfactant under the influence of gravitational, capillary and van der Waals forces. We prove the existence of global weak solutions for \emph{medium sized} initial data in \emph{large function spaces}. Moreover, exponential decay towards the flat equilibrium state is established, where an estimate on the decay rate can be computed explicitly.
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On a thin film model with insoluble surfactant
Gabriele Bruell
Institute for Analysis, Karlsruher Institute of Technology (KIT), D-76128 Karlsruhe, Germany
and
Rafael Granero-Belinchón
Departamento de Matemáticas, Estadística y Computación, Universidad de Cantabria. Avda. Los Castros s/n, Santander, Spain.
Abstract.
This paper studies the existence and asymptotic behavior of global weak solutions for a thin film equation with insoluble surfactant under the influence of gravitational, capillary and van der Waals forces. We prove the existence of global weak solutions for medium sized initial data in large function spaces. Moreover, exponential decay towards the flat equilibrium state is established, where an estimate on the decay rate can be computed explicitly.
Key words and phrases:
Thin film equations; Surfactant; System of quasilinear parabolic equations; Degenerate equations; Global weak solutions; Decay rates
2010 Mathematics Subject Classification:
35D30, 35B40, 35K52, 35K65, 76A20
Date:
1. Introduction
Surfactant is the short form for surface active agent and is a substance which – in contact with a fluid – reduces surface tension. The induced dynamic is twofold: On the one hand, the resulting surface tension gradients influence the evolution of the thin film; on the other hand, the surfactant speads along the surface. The latter effect is known as Marangoni effect. Naturally, the surfactant induced dynamics are of particular interest in connection with thin fluid films, where surface tension forces have a very important impact. In particular, the interest in thin film equations with a layer of surfactant on the surface is motived by various applications. For instance coating flow technology, film drainage in emulsions, foams and medical treatment of lungs of premature infants.
The present work studies the dynamics of a viscous, incompressible, Newtonian thin film over a flat bottom equipped with a layer of insoluble surfactant on the free surface. Thus, to study the full problem on has to consider a free boundary problem for the Navier-Stokes equations coupled with an advection-diffusion equation on the free surface. As this is a challenging issue, a common approach to simplify the problem is to consider the lubrication approximation to derive evolution equations for the film height and the surfactant concentration which capture the behavior and the main properties of the full free boundary problem. Pioneering works in this direction in absence of surfactant effects are due to Greenspan [32], Constantin, Dupont, Goldstein, Kadanoff, Shelley & Zhou [13], Bernis & Friedman [4], Beretta, Bertsch & Dal Passo [3] and Bertozzi & Pugh [5]. Also, Escher, Matioc & Matioc [23] considered the flow in porous media (see also Escher & Matioc [25], Matioc [39], Escher, Laurençot & Matioc [21], Laurençot & Matioc [35, 36, 37, 38] and Bruell & Granero-Belinchón [10]) while the Stokes flow was considered by Escher, Matioc & Matioc [24] (see also Escher & Matioc[26] and Bruell & Granero-Belinchón [10]). A more recent reference is Pernas-Castaño & Velázquez [40], where the authors study the evolution of the interface between two different fluids in two concentric cylinders when the velocity is given by the Navier-Stokes equation and one of the fluids is thin.
Some of the main works on the evolution of a thin film with insoluble surfactant are the ones by Borgas & Grotberg [6], Gaver & Grotberg [29] and Jensen & Grotberg [34]. Under certain assumptions, Jensen & Grotberg [34] applied the lubrication approximation and cross-sectional averaging to derive the following system of evolution equations for the film height and the surfactant concentration :
[TABLE]
Here, denotes the time-space domain for the unknown functions and , with being an open, bounded interval. The system (1) is supplemented with initial conditions
[TABLE]
where and are given functions and boundary conditions
[TABLE]
The appearing parameters represent a modified gravitational constant (), surface tension coefficient (), Hamaker constant (), which corresponds to the effects of van der Waals forces, and surface diffusion coefficient (). Moreover, is the constitutive equation of state relating the surface tension to the surfactant concentration. As the presence of surfactant reduces surface tension, is assumed to be positive and nonincreasing. A commonly used description for the dependence of the surface tension on the surfactant is given by (cf. [42, 6, 29])
[TABLE]
for . For simplicity reasons, in the present work, we assume that is given by the limit for in , that is
[TABLE]
This assumption is also used in applications and numerical investigations; see for instance [33, 1, 2, 44, 45].
Let us mention that the scaling Jensen and Grotberg used for the surfactant concentration is given by
[TABLE]
where is the so-called critical micelle concentration. If the surfactant concentration exceeds the value , the molecules form micelles and thus there is no further decrease of surface tension to perceive. Consequently, it is natural to assume that the initial surfactant concentration satisfies .
From the analytical point of view, the system (1) includes many challenges. Notice that the evolution equations in (1) form a system of two strongly coupled, degenerate, parabolic partial differential equations. Under the assumption that all the appearing parameters and are positive, the degeneracy occurs in the equation for the film height, when approaches zero, i. e. when the surface touches the bottom. Moreover, (1) is a coupled system of mixed orders having cross diffusive terms. While the equation for the surfactant concentration is an avection-diffusion equation of second order, the equation for the film height is of fourth order. Notice that, if capillary effects are neglected (), then the system is of second order in both equation. In our considerations, we are going to consider both cases: The gravity driven film () and the capillary driven film .
Even if during the last decades modeling as well as numerical investigations for the thin film equation with surfactant have attracted lots of attention (see for instance [29, 34, 33, 1, 2, 44, 16] and the references therein), the rigorous analytical studies have started recently. Existence of local solutions for a thin film equation with insoluble surfactant driven by Marangoni forces only () has been studied by Renardy [41]. In absence of capillary and van der Waals forces (), the authors Escher, Hillairet, Laurençot & Walker [18] used lubrication approximation to derive a system of differential equations describing the evolution of a thin film with soluble surfactant under the influence of Marangoni and gravitational forces. Moreover, they proved local well-posedness in the space of square integrable functions by means of semigroup theory as well as asymptotic stability with exponential decay of the equilibrium. We would like to emphasize that their stability result is stated for positive initial data in the -based Sobolev space . The result shows in particular, that starting with data close to the flat steady state there exists a unique global strong solution. A similar result for a two-phase thin film equation with insoluble surfactant was shown by Bruell [7] for the gravity () as well as for the capillary driven film (). Due to the degeneracy of the equation with respect to the film height, it is natural to expect that in general strong solutions exist only locally in time. The existence of nonnegative global weak solutions for the thin film equation with insoluble surfactant was proved by Escher, Hillairet, Laurençot & Walker [17] for the gravity driven thin film (), and [19] for the corresponding capillary driven film () and by Bruell [8] for the two-phase thin film equation with insoluble surfactant under the influence of capillary forces (see also [28, 12]). The main ingredient in all these works concerning the existence of global weak solutions is a regularization argument to overcome the degeneracy, followed by a two-step compactness argument based on a priori estimates provided by an energy functional for the system. Finally, we would like to mention that traveling wave solutions of a gravity thin film equation with insoluble surfactant () were studied by Escher, Hillairet, Laurençot & Walker [20] (see also [22]).
1.1. Aim and outline of the present paper
The aim of the present work is to prove the existence of global weak solutions of (1) under fairly low regularity assumptions with respect to the initial data. Similar as in the companion paper [10], we work in scales of Wiener spaces. Exploiting the algebra inequality verified by the norms of the underlying spaces, we show a priori energy estimates in Wiener algebra, which guarantee the existence of global weak solutions and imply the exponential decay towards the flat equilibrium state. Moreover, the decay rate can be bounded by explicit constants, which depend on the parameters of the system and the size of the initial data. In addition we prove uniqueness of the weak solutions provided that they belong to a (slightly) higher regularity class. A similar approach has been employed before for the Muskat problem [27, 14, 15] (and the references therein) for the doubly parabolic Keller-Segel system [11], PDEs modelling small steepness porous flow [31] and the evolution of crystal surfaces [30]. We consider two cases: The gravity driven film, where surface tension effects are neglected (), which leads to a coupled system of second order equations; and the capillary driven film, where we take surface tension effects into account (). In the latter case the evolution equations (1) build a coupled system of mixed orders. Let us emphasize that in our work we take all acting forces (gravity, surface tension, van der Waals) into account. To the best of our knowledge this is the first analytical existence result for the full system (1) where . The outline of the paper is as follows: We start in Section 2 with some preliminaries and auxiliary results concerning the scale of Wiener spaces. In Section 3 we reformulate the problems in terms of the distance to the (flat) equilibrium and state our main results. Eventually Sections 4 and 5 are devoted to the proofs of the main theorems for the gravity () and capillary () driven flow, respectively.
2. Preliminaries
We start by introducing the functional analytical framework. Let . For we denote by
[TABLE]
the standard -based Sobolev spaces on . We recall the expression of the th Fourier coefficient and the Fourier series of a periodic integrable function ,
[TABLE]
We introduce the Wiener spaces as
[TABLE]
We note that is a Banach algebra and form a Banach scale. Furthermore, the following inequalities hold true:
- •
Let , then
[TABLE]
- •
Let be a fixed parameter and , then, due to the convexity of in this range,
[TABLE]
while, as a consequence of subadditivity of , for , we have
[TABLE]
- •
Due to the Hölder inequality, we have the following interpolation inequality
[TABLE]
3. Reformulation of the problem and main results
3.1. Reformulation
In what follows we assume that . Then, system (1) is given by
[TABLE]
with initial conditions
[TABLE]
and boundary conditions
[TABLE]
The problem is posed on a spatial interval with the above lateral boundary conditions. However, without lossing generality, instead of considering an interval and no-flux boundary conditions, we are going to consider periodic solutions of (7) on a flat torus (which can be identified with ). This generalization actually simplifies our approach and it was already used in [10] for similar problems. Let us explain why our formulation in the flat torus is actually equivalent to the original problem posed on the interval . If are the initial data on an interval satisfying the boundary conditions (8), we set
[TABLE]
In view of the symmetry of (7), the evenness of initial data is preserved and any solution of (7) on with initial data satisfying the boundary conditions (8), can be identified with the corresponding solution to even initial data on the periodic cell restricted to the half-domain . In the sequel we drop the bar notation and consider periodic solutions of (7) defined on with initial conditions
[TABLE]
where are given periodic functions. It follows immediately from the structure of the equations (7) that the initial mass is preserved in time:
Lemma 1** (Conservation of mass).**
Let be a solution of (7) on a time interval , then
[TABLE]
If are nonnegative bounded initial data, we set
[TABLE]
The constants and represent the mean of the initial data and they are a steady state of the system (7). In our studies we consider the evolution of the distance of a solution to the steady state . For this purpose, we define new unknowns
[TABLE]
which have zero mean. In the new variables (9), the system (7) can be rewritten as
[TABLE]
with initial conditions
[TABLE]
where and are the initial displacement functions from the flat states and , respectively. The nonlinear terms , on the right hand side of (10) are defined as
[TABLE]
Note that, for , we have
[TABLE]
Consequently, under the assumption that
[TABLE]
we can use (11) and (12) and write
[TABLE]
Similarly, invoking (12) and (13) we have that
[TABLE]
We fix the initial data , for problem (7). Thereby, the constants and are uniquely determined and we are going to state our results in terms of , for (10).
3.2. Main results
In what follows the constants representing the gravitational and van der Waals forces as well as the diffusion coefficient are assumed to be strictly positive.
Definition 1**.**
Set for the capillary driven flow () and for the gravity driven flow ().We say that is a weak solution of (10) on corresponding to initial data if and only if
[TABLE]
and
[TABLE]
for all , where denotes the operator given by .
Let . For , we define the following functional:
[TABLE]
We start by formulating our main result for the gravity driven flow, that is when . To this end, let us define
[TABLE]
and the constants
[TABLE]
Then, we have the following result:
Theorem 1** (Global existence for ).**
Let be nontrivial initial data for (10) such that
[TABLE]
Assume that . If
[TABLE]
then there exists at least one global solution of (10) in the sense of Definition 1 with regularity
[TABLE]
for any and . Moreover, the weak solution satisfies the following exponential decay:
[TABLE]
where
[TABLE]
Furthermore, if the solution satisfies the regularity
[TABLE]
then the weak solution is unique.
Remark 1**.**
The condition in Theorem 1 implies in particular that
[TABLE]
This corresponds to a positivity condition of and and ensures that (14) is initially satisfied.
Remark 2**.**
Note that the size restriction is explicitly computable and that the initial data do not need to be small in Sobolev spaces (one should compare the results in this paper with the global result in [9]). In particular, we prove the existence global weak solutions and their decay towards the flat state for highly oscillating initial data. Let us further explain this with an explicit example. Consider the case where van der Waals forces are neglected, that is and set . We choose the initial data to be
[TABLE]
for . Then,
[TABLE]
and the constants and are given by
[TABLE]
Then, for , this family of initial data satisfies the hypotheses and Theorem 1 guarantees the existence of a global weak solution corresponding to the initial data . Moreover the solution decays exponentially towards the flat equilibrium and
[TABLE]
where . Furthermore, observe that
[TABLE]
Next we formulate our main theorem for the capillary driven flow, that is for the full system (7) with . In addition to (18)–(21), we define
[TABLE]
Then, we have the following result:
Theorem 2** (Global existence for ).**
Let be nontrivial initial data for (10) such that
[TABLE]
Assume that . If
[TABLE]
then there exists at least one global solution of (10) in the sense of Definition 1 with regularity
[TABLE]
for any and . Moreover, the weak solutions satisfies the following exponential decay:
[TABLE]
where
[TABLE]
Furthermore, if the solution satisfies the regularity
[TABLE]
then the weak solution is unique.
The remainder or this paper is devoted to the proof of the above theorems.
4. Proof of Theorem 1: Global existence and decay when
Let us start by outlining the steps of the proof. First, we provide in Subsection 4.1 some a priori estimates of a solution of (10). Under the assumptions on the initial data in Theorem 1, which in particular require that
[TABLE]
we will show that the solution preserves this estimate, that is
[TABLE]
Notice that the above inequality implies that
[TABLE]
[TABLE]
Hence, the positivity conditions for and ,
[TABLE]
are preserved for all . Then we obtain that, for small enough initial energy , the following inequality holds:
[TABLE]
for some dependent on the initial data. This inequality implies that a local solution can not leave a ball in ; thus, there is no finite time singularity in these functional spaces. In Subsection 4.2 we implement a standard Galerkin approximation argument to prove the existence of global weak solutions. The existence of a classical local solution of the Galerkin approximated sytem is guaranteed by the Picard–Lindelöf Theorem. These approximated solutions are analytic. In particular, they satisfy
[TABLE]
where denotes the maximal time of existence of . The a priori estimates from before ensure the global existence of the approximated solutions and provide the necessary a priori bounds in order to use compactness arguments and pass to the limit , which yields a global weak solution of (10) in the sense of Definition 1. Now, let be such approximate solution corresponding to the initial data , which satisfy the hypothesis of Theorem 1, then, in view of the Poincaré-like inequality in (4), we see that is a Lyapunov functional, i.e., that
[TABLE]
The latter implies the exponential decay towards the equilibrium for the global weak solution (see Subsection 4.3). Eventually, in Subsection 4.4 it is shown that a global weak solution in
[TABLE]
is unique.
4.1. A priori estimates in :
Let and
[TABLE]
be a local solution of (10) with initial data
[TABLE]
satisfying the condition
[TABLE]
By continuity there exists such that the above estimate is satisfied on , that is
[TABLE]
Let us moreover assume that is the maximal time such that (26) holds true on . Hence, either
[TABLE]
or . Notice that the restriction (14) holds true on the time interval . In the following let . We compute
[TABLE]
so, using that ,
[TABLE]
We recall that
[TABLE]
and by the hypothesis of the theorem
[TABLE]
Using the algebra property of the Wiener space , i.e.
[TABLE]
together with the interpolation inequality
[TABLE]
the contribution of the nonlinear terms , and , can be estimated as
[TABLE]
[TABLE]
and
[TABLE]
where we used the convergence of the geometric series for , and
[TABLE]
Similarly, the nonlinear terms , and are bounded by
[TABLE]
[TABLE]
[TABLE]
Grouping terms, we find that
[TABLE]
We recall the definition (20) and (21), then we add equations (28) and (29), use the previous estimates for , and 8 and obtain that
[TABLE]
for , with and defined in (18) and (19), respectively. Using the hypothesis of the Theorem 1, we have that
[TABLE]
so, there exists a time such that
[TABLE]
Let us assume that is the maximal times such that (31) holds true on We want to propagate this decay for all times, that is, we aim to show that , which in turn implies that , by (27). Let us emphasize that for guarantees that
[TABLE]
Thereby, for any we have that
[TABLE]
[TABLE]
In particular, we obtain that
[TABLE]
Assume that . By continuity, we deduce that , but this implies that, again,
[TABLE]
and that contradicts the assumption . Thus, we have shown that in fact
[TABLE]
and thereby , in view of (27). Then,
[TABLE]
where . Eventually, the energy estimate for the gravity driven equation () reads
[TABLE]
and
[TABLE]
for all , where is a constant depending on the initial data.
4.2. Existence of global weak solutions
We use a standard Galerkin approximation to obtain in the limit a global weak solution of (10) where surface tension effects are neglected, i. e. . Let us fix . Set
[TABLE]
and the initial data
[TABLE]
to coincide with the Fourier truncation of the and , respectively. Recall that the convergence of the Fourier series of the initial data is guaranteed by the assumption that . We consider the Galerkin approximated problems:
[TABLE]
where the nonlinearities are given by
[TABLE]
Here, the operator denotes the Fourier truncation operator
[TABLE]
The Picard–Lindelöf Theorem ensures the existence of classical solutions
[TABLE]
where is the maximal existence time. Furthermore, the approximated problems provide the same a priori bounds as in the previous sections. Consequently the Galerkin solutions exist globally and for any we have the bounds:
[TABLE]
and
[TABLE]
Following the lines in [10], the above uniform regularities of the Galerkin approximations guarantee the existence of a weakly convergent subsequences (not relabeled) such that
[TABLE]
Similarly, using interpolation in Wiener spaces, the finite measure of the spatial domain and the fact that for any , we obtain the existence of a subsequence (not relabeled), such that
[TABLE]
From the previous fact we can infer that actually
[TABLE]
Furthermore (35), (36) imply that
[TABLE]
which is due to for any and an interpolation inequality for fractional Sobolev spaces. Eventually, as a consequence of (35),(36) and a compactness argument as in [43, Corollary 4], we obtain (up to a subsequence) that
[TABLE]
Passing to the limit in the weak formulation of the Galerkin approximation yields the existence of a global weak solution of (10) in the sense of Definition 1.
4.3. Exponential trend to equilibrium
Using (30) and the definition of in (25), we have that
[TABLE]
Using the Poincaré-like inequality (4), we also conclude that
[TABLE]
which in turn implies the exponential decay towards the equilibrium:
[TABLE]
Using (37) and the lower semi-continuity of the weak convergence, we have that
[TABLE]
4.4. Uniqueness
The proof follows a standard contradiction argument. For the sake of brevity, we only sketch the idea. Assume that there exist two different solutions and starting from the same initial data
[TABLE]
Assume also that these solutions satisfy
[TABLE]
Using the smallness of the initial data, the same estimates as in Subsection 4.1 yield that
[TABLE]
Now the statement is a consequence of Gronwall’s inequality and the fact that .
5. Proof of Theorem 2: Global existence and decay when
The proof essentially follows the arguments in the previous section, the main difference relying in the fact that for we have that (10) is a system of mixed orders. Thereby the energy estimates require some additional investigation. The existence of local solutions of the approximated Galerkin systems are straightforward due to Picard–Lindelöf’s theorem (see Subsection 4.2). The energy estimates then ensure that the approximated solutions exist globally. Furthermore, the energy estimates provide the necessary a priori bounds to pass to the limit in the Galerkin approximation; thereby guaranteeing the existence of a global weak solution in the sense of Definition 1. In view of the weak lower semicontinuity of the norm, the global weak solution inherits the energy estimates for the approximated solutions and we can conclude the regularity and exponential decay of the solution.
5.1. A priori estimates in :
To perform our energy estimates let us assume that there exists a local solution
[TABLE]
of the fourth-order system (10) where , corresponding to initial data , satisfying
[TABLE]
Similar as before, we have that
[TABLE]
Keeping in mind the definitions of , in (20), (21), and (24), we take the sum of the two inequalities above and obtain that
[TABLE]
Recalling (30), we have that
[TABLE]
where and are defined in (18) and (19), respectively. Thus we are left to estimate the remaining terms and . Similarly as before, using the interpolation inequality in Wiener spaces, we estimate
[TABLE]
and
[TABLE]
Note that by Young’s inequality, we have that
[TABLE]
for any . In particular, as and are nonzero (provided the initial data are nontrivial), we can take
[TABLE]
Thus,
[TABLE]
Then, we conclude that
[TABLE]
Using (23), we can group terms as follows:
[TABLE]
Repeating the argument from Section 4, we conclude that
[TABLE]
where is defined in (25). The energy estimate for the capillary driven thin film () reads
[TABLE]
and
[TABLE]
for all , where is a constant depending on the initial data.
5.2. Existence of global weak solutions
In a similar way as in Subsection 4.2, we obtain the existence of a sequence of global Galerkin approximations . Then, the energy estimates from above guarantee that for any :
[TABLE]
and
[TABLE]
Moreover, the time derivatives satisfy
[TABLE]
for any . Consequently, we obtain the existence of a subsequence (not relabeled) such that
[TABLE]
Moreover,
[TABLE]
and
[TABLE]
Equipped with these convergences we can pass to the limit in the weak formulation and conclude the global existence of a weak solution of (10) for in the sense of Definition 1.
5.3. Exponential trend to equilibrium
The proof follows the same ideas as in Subsection 4.3. The sequence of Galerkin approximation satisfies the energy estimates. In particular, we have the exponential decay towards the equilibrum in (41):
[TABLE]
where is defined in (25). Using (42) and the lower semi-continuity of the weak convergence, we have that
[TABLE]
for all , which proves the claim.
5.4. Uniqueness
Also the proof for the conditional uniqueness is similar to the one in Subsection 4.4. Assume that there exist two different solutions and starting from the same initial data
[TABLE]
Moreover, we suppose that the solutions satisfy the additional regularity
[TABLE]
for . Similar as for the energy estimate we compute that
[TABLE]
Now the assertion follows by applying Gronwall’s inequality and recalling that the solutions share the same initial data.
Acknowledgements
The author R.G.B was partially supported by the LABEX MILYON (ANR-10-LABX-0070) of Université de Lyon, within the program “Investissements d’Avenir” (ANR-11-IDEX-0007) operated by the French National Research Agency (ANR). The author G.B. gratefully acknowledges the funding by the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation)- Project ID 258734477 - SFB 1173. Part of this research was carried out while G.B. was supported by grant no. 250070 from the Research Council of Norway and during a short stay of G.B. at Institut Camille Jordan under project DYFICOLTI, ANR-13-BS01-0003-01 support.
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