All-optical detection of periodic structure of chalcogenide superlattice using coherent folded acoustic phonons

TL;DR

This paper demonstrates an all-optical, non-destructive method to determine the periodic structure of chalcogenide superlattices by analyzing coherent folded acoustic phonons excited by femtosecond laser pulses, revealing structural details and intermixing.

Contribution

It introduces a novel optical technique using coherent folded acoustic phonons to characterize superlattice structures at atomic resolution.

Findings

Peak frequency of FLA modes varies with GeTe layer thickness

Elastic continuum model accurately reproduces FLA mode behavior

Discovery of a new superlattice structure indicating Ge atom intermixing

Abstract

Chalcogenide superlattices (SL) consist of alternate stacking of GeTe and Sb$_{2}$Te$_{3}$ layers. The structure can become a 3D topological insulator depending on the constituent layer thicknesses, making the design of the SL period a central issue for advancing chalcogenide SL as potential candidates for spin devices as well as for optimization of the current generation of phase-change memory devices. Here we explore the periodic structure of chalcogenide SL by observing coherent folded longitudinal acoustic (FLA) phonons excited by femtosecond laser pulse irradiation. The peak frequency of the FLA modes was observed to change upon variation of the thickness of the GeTe layer, which was well reproduced by means of an elastic continuum model. In addition, a new SL structure is unveiled for a sample consisting of thin GeTe and Sb$_{2}$Te$_{3}$ layers, which suggests intermixing of Ge atoms. This all-optical technique based on observation of coherent FLA modes offers a non-destructive characterization of superlattice structures at atomic resolution.