# Basis Glass States: New Insights from the Potential Energy Landscape

## TL;DR

This paper introduces the concept of basis glass states derived from the potential energy landscape, explaining their role in the thermally activated dynamics, glass transition, and aging processes in glass-forming systems.

## Contribution

It proposes a novel framework of basis glass states that tile the configuration space and describe glass dynamics and transitions.

## Key findings

- Basis glass states are confined to single metabasins.
- They tile the entire configuration space.
- The probability distribution over these states describes glass transition and aging.

## Abstract

Using the potential energy landscape formalism we show that, in the temperature range in which the dynamics of a glass forming system is thermally activated, there exists a unique set of "basis glass states" each of which is confined to a single metabasin of the energy landscape of a glass forming system. These basis glass states tile the entire configuration space of the system, exhibit only secondary relaxation and are solid-like. Any macroscopic state of the system (whether liquid or glass) can be represented as a superposition of basis glass states and can be described by a probability distribution over these states. During cooling of a liquid from a high temperature, the probability distribution freezes at sufficiently low temperatures describing the process of liquid to glass transition. The time evolution of the probability distribution towards the equilibrium distribution during subsequent aging describes the primary relaxation of a glass.