An Introduction to the Holstein-Primakoff Transformation, with Applications in Magnetic Resonance
J.A. Gyamfi

TL;DR
This paper introduces the Holstein-Primakoff transformation as a powerful theoretical tool for simulating multispin magnetic resonance spectra, connecting quantum spin systems to combinatorics to improve computational approaches.
Contribution
It provides a comprehensive, accessible introduction to the Holstein-Primakoff transformation and demonstrates its application in reformulating complex multispin Hamiltonian problems as combinatorial tasks.
Findings
Holstein-Primakoff transformation links spin systems to graph theory and number theory.
Reformulation of multispin Hamiltonian problems as combinatorial problems.
Enhanced methods for characterizing and eigendecomposing multispin Hamiltonians.
Abstract
We have witnessed an impressive advancement in computer performance in the last couple of decades. One would therefore expect a trickling down of the benefits of this technological advancement to the borough of computational simulation of multispin magnetic resonance spectra, but that has not been quite the case. Though some significant progress has been made, chiefly by Kuprov and collaborators, one cannot help but observe that there is still much to be done. In our view, the difficulties are not to be entirely ascribed to technology, but, rather, may mostly stem from the inadequacy of the conventional theoretical tools commonly used. We introduce in this paper a set of theoretical tools which can be employed in the description and efficient simulation of multispin magnetic resonance spectra. The so-called Holstein-Primakoff transformation lies at the heart of these, and provides a…
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Taxonomy
TopicsMolecular spectroscopy and chirality
