Topologically nontrivial Andreev bound states
Pasquale Marra, Muneto Nitta

TL;DR
This paper predicts the existence of topologically nontrivial Andreev bound states in one-dimensional superconductors, characterized by a new particle-hole Chern number, distinct from Majorana states, due to a synthetic two-dimensional topological space.
Contribution
The authors introduce a novel topological invariant, the particle-hole Chern number, to describe nontrivial Andreev bound states in 1D superconductors, expanding the understanding of topological phases.
Findings
Topologically nontrivial Andreev bound states can coexist with Majorana states.
These states are characterized by a particle-hole Chern number in a synthetic 2D space.
Nontrivial Andreev states have distinct spectral signatures and are topologically different from Majorana states.
Abstract
Andreev bound states are low energy excitations appearing below the particle-hole gap of superconductors, and are expected to be topologically trivial. Here, we report the theoretical prediction of topologically Andreev bound states in one-dimensional superconductors. These states correspond to another topological invariant defined in a synthetic two-dimensional space, the particle-hole Chern number, which we construct in analogy to the spin Chern number in quantum spin Hall systems. Nontrivial Andreev bound states have distinct features and are topologically nonequivalent to Majorana bound states. Yet, they can coexist in the same system, have similar spectral signatures, and materialize with the concomitant opening of the particle-hole gap. The coexistence of Majorana and nontrivial Andreev bound state is the direct consequence of "double dimensionality", i.e., the…
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Topologically nontrivial Andreev bound states
Pasquale Marra
Muneto Nitta
Department of Physics, and Research and Education Center for Natural Sciences, Keio University, 4-1-1 Hiyoshi, Yokohama, Kanagawa 223-8521, Japan
Abstract
Andreev bound states are low energy excitations appearing below the particle-hole gap of superconductors, and are expected to be topologically trivial. Here, we report the theoretical prediction of topologically nontrivial Andreev bound states in one-dimensional superconductors. These states correspond to another topological invariant defined in a synthetic two-dimensional space, the particle-hole Chern number, which we construct in analogy to the spin Chern number in quantum spin Hall systems. Nontrivial Andreev bound states have distinct features and are topologically nonequivalent to Majorana bound states. Yet, they can coexist in the same system, have similar spectral signatures, and materialize with the concomitant opening of the particle-hole gap. The coexistence of Majorana and nontrivial Andreev bound state is the direct consequence of “double dimensionality”, i.e., the dimensional embedding of the one-dimensional system in a synthetic two-dimensional space, which allows the definition of two distinct topological invariants ( and ) in different dimensionalities.
Topological phases and their low energy excitations have unprecedented and exotic properties, which partially mimic those of elementary particles in high-energy physics, and may have broad implications for technological applicationshasan_colloquium_2010 ; qi_topological_2011 . Prominent examples are the chiral modes and helical modes realized respectively in quantum Hallklitzing_new_1980 ; laughlin_quantized_1981 ; thouless_quantized_1982 and quantum spin Hall insulatorskane_quantum_2005 ; kane__2005 ; sheng_spin_2005 ; sheng_quantum_2006 ; bernevig_quantum_2006 , and the Majorana modes in topological superconductorskitaev_unpaired_2001 ; alicea_new_2012 ; leijnse_introduction_2012 ; beenakker_search_2013 ; stanescu_majorana_2013 ; sato_topological_2017 ; aguado_majorana_2017 . The connection between topology and low energy excitations is enforced by the bulk-edge correspondencehatsugai_chern_1993 ; imura_bulk-edge_2018 , which relates the topological invariants defined in a -dimensional space to the nontrivial modes confined in a lower dimensionality. Remarkably, topological properties can transcend the spatial dimensions of the physical system, in the sense that the topological invariants may be defined in synthetic dimensionskraus_quasiperiodicity_2016 ; ozawa_topological_2019 , i.e., additional continuous degrees of freedom which are induced by spatially varying fields in condensed matterkraus_four-dimensional_2013 ; park_fractional_2016 ; thakurathi_fractional_2018 , in particular topological superconductorskjaergaard_majorana_2012 ; klinovaja_transition_2012 ; li_manipulating_2016 ; marra_controlling_2017 , or can be engineered, e.g., in cold atoms in optical latticesprice_four-dimensional_2015 ; lohse_exploring_2018 ; celi_synthetic_2014 ; marra_fractional_2015 ; nakajima_topological_2016 ; lohse_thouless_2016 ; marra_fractional_2017 ; zilberberg_photonic_2018 . In Josephson junctions, synthetic dimensions can generate nontrivial topological objects such as Weyl points and nonstandard Andreev bound statesriwar_multi-terminal_2016 ; houzet_majorana-weyl_2019 ; kotetes_synthetic_2019 .
Additional synthetic dimensions allow the existence of otherwise impossible topological phases. For example, topological invariants defined in a one-dimensional (1D) space with no symmetries are necessarily trivialschnyder_classification_2009 ; kitaev_periodic_2009 ; ryu_topological_2010 . Nevertheless, 1D systems such as Thouless quantum pumps exhibit nontrivial phases corresponding to a topological invariant, the Chern number, defined in a synthetic 2D spacethouless_quantization_1983 . On top of that, there is another possibility: Synthetic dimensions may allow the coexistence of distinct topological phases characterized by distinct topological invariants, defined in spaces with different dimensions. Indeed, a -dimensional system embedded in a synthetic -dimensional space can be described by two distinct topological invariants, e.g., and , defined in and dimensions, and hence occupies two different entries of the periodic table of nontrivial phasesschnyder_classification_2009 ; kitaev_periodic_2009 ; ryu_topological_2010 . Such “double dimensionality” may realize, in principle, the coexistence of topologically nonequivalent phases with strikingly different properties.
In this Rapid Communication, we theoretically demonstrate the coexistence of two topologically distinct phases in 1D superconductors due to the dimensional embedding in a 2D synthetic space. These topological phases correspond to distinct topological invariants: The familiar Majorana number , defined in the physical 1D space, and the particle-hole (PH) Chern number , defined in a synthetic 2D space, which we construct in analogy to the spin Chern number in quantum spin Hall systemskane_quantum_2005 ; kane__2005 ; sheng_spin_2005 ; sheng_quantum_2006 ; bernevig_quantum_2006 . These invariants correspond respectively to Majorana bound states (MBS) and topologically nontrivial Andreev bound states (ABS). Nontrivial ABS are distinct and topologically nonequivalent to MBS and, unlike trivial ABSasano_phenomenological_2004 ; tanaka_theory_2005 ; golubov_andreev_2009 ; tanaka_anomalous_2010 ; liu_zero-bias_2012 ; kells_near-zero-energy_2012 ; roy_topologically_2013 ; stanescu_disentangling_2013 ; cayao_sns_2015 ; san-jose_majorana_2016 ; liu_andreev_2017 ; liu_distinguishing_2018 ; moore_two-terminal_2018 ; moore_quantized_2018 ; fleckenstein_decaying_2018 ; awoga_supercurrent_2019 , are fully spin and PH polarized, and protected by PH symmetry. Moreover, we will show how these distinct topological phases can be realized in a realistic system, i.e., in magnetic atom chains on a conventional superconductor, and we will discuss the differences and similarities between nontrivial ABS and MBS, which are relevant for their experimental realization and identification.
We thus consider a chain of magnetic atomsklinovaja_topological_2013 ; braunecker_interplay_2013 ; vazifeh_self-organized_2013 ; pientka_topological_2013 ; poyhonen_majorana_2014 ; pientka_unconventional_2014 ; choy_majorana_2011 ; nadj-perge_proposal_2013 on the surface of a conventional superconductor, in the presence of a helical spin orderkim_toward_2018 and an externally applied Zeeman field, as in Fig. 1. The essential physics is described by a Bogoliubov-de Gennes tight-binding Hamiltonian, which reads
[TABLE]
where is the Nambu spinor. Here, is the intrinsic spin-orbit coupling (SOC) due to the inversion symmetry breaking at the surface, the spin-singlet superconducting pairing induced by the substrate, and the total Zeeman field at each site.
The helical spin order is induced by the Ruderman-Kittel-Kasuya-Yosida (RKKY) coupling between localized magnetic moments of the chain, and is resonantly enhanced by the perfect nesting between Fermi momenta in 1D systems. This nesting condition fixes the spatial frequency of the helix as braunecker_nuclear_2009 ; braunecker_spin-selective_2010 , which mandates , which we assume hereafter. This assumption is however not essential to the main resultssupp . Moreover, in the absence of externally applied fields, the spin helix direction is fixed by symmetry. Indeed, the SOC (along ) breaks the spin-rotation symmetry down to rotations in the plane: Hence, the helical order becomes pinned to the plane for applied fields smaller than the SOC splittingli_manipulating_2016 . For simplicity, we assume that the helical order is independent of the externally applied field. Thus, the total field is , where is the applied field and . Here, , , and are respectively the spatial frequency, phase-offset, and magnitude of the field induced by the helical spin order. The cases with and reduce respectively to the well-known regimes where only the uniformoreg_helical_2010 ; lutchyn_majorana_2010 and helical fieldschoy_majorana_2011 ; kim_helical_2014 ; nadj-perge_proposal_2013 are present. If the applied and helical fields are not perpendicular , the total field is amplitude-modulated, , and depends explicitly on the phase-offset , which cannot be absorbed by local or global unitary rotations of the spin basisbraunecker_spin-selective_2010 ; choy_majorana_2011 . Thus, the energy spectrum and the PH gap depend on the phase-offset . Since we are interested in this regime, we assume that the applied field is coplanar with the helical field. Besides, one can always rotate the spin basis such that the applied field is parallel to the axis, which we assume hereafter. Note that, assuming a rigid and uniformly rotating spin helix, the magnetic order is degenerate in the phase-offset , even with external fields , since the coupling between the applied field and the helical order vanishes, being the total magnetization . However, the effect of the applied field on the spin helix may induce a finite magnetization and break the invariance. If these effects are negligible, the phase-offset will become pinned by arbitrarily small local variations of the Zeeman field or by defects and impurities along the chain. Note also that the SOC induces spin-triplet correlationsheimes_interplay_2015 , which we consider in the Supplemental Materialsupp .
In order to define the topological invariants, it is useful to Fourier-transform the Hamiltonian (1), which yields
[TABLE]
where and . We notice that for , Eq. 2 reduces to the Harper-Hofstadter Hamiltonian realized in topological quantum pumpsharper_single_1955 ; hofstadter_energy_1976 ; thouless_quantization_1983 ; hatsugai_energy_1990 . Due to the coupling between different momenta, the Hamiltonian is invariant up to momenta translations . Assuming a spatial frequency commensurate to the lattice, i.e., with integer coprimes, this symmetry induces a periodicity in momentum space and a folding of the energy levels into a reduced Brillouin zone (BZ) .
The model exhibits PH symmetry and broken time-reversal symmetry at any finite field, and belongs to the Altland-Zirnbauerschnyder_classification_2009 ; kitaev_periodic_2009 ; ryu_topological_2010 symmetry class D. Note that PH symmetry acts as in the synthetic BZ (see Supplemental Materialsupp ). Gapped phases in 1D are characterized by a topological invariant, the Majorana numberkitaev_unpaired_2001 , defined as where are the projections of the Hamiltonian in the Majorana basis onto the subspace spanned by the momenta , with the projector operators, and the time-reversal symmetry points.
Phase transitions between trivial and nontrivial phases are determined by the closing of the PH gap, i.e., for either or . For clarity, we will focus here only on the phases which are globally gapped, i.e., where the PH gap is finite for any value of the phase-offset . We define the global PH gap as . Globally gapped phases are either trivial or nontrivial. Conversely, phases which are not globally gapped , i.e., where the PH gap closes for some values of the phase-offset, may be trivial and nontrivial depending on the phase-offset (see Ref. marra_controlling_2017 ). In Fig. 2(a) we plot the value of the global PH gap as a function of the helical field magnitude and applied field , calculated by direct numerical diagonalization of the Hamiltonian (2) for (i.e., ). The globally gapped phases are separated by domains where the global PH gap vanishes. We then calculate the Majorana number numerically for each globally gapped phase. Due to time-reversal symmetry, the phase at zero field (and at small fields ) is obviously trivial. At larger fields, there are two separated (but topologically equivalent) nontrivial phases with , which are realized respectively for strong applied fields and small (or zero) helical fields , and for strong helical fields and small (or zero) applied fields . The two separated phases with reduce to the well-known regimes where only a uniform fieldoreg_helical_2010 ; lutchyn_majorana_2010 (with and ), or the helical fieldchoy_majorana_2011 ; nadj-perge_proposal_2013 (with and ) are present. In these regimes, topological superconductivity is realized respectively for , with [the axis in Fig. 1(a)] and for where and [the axis in Fig. 1(a)], as one can show by unitary rotating Eq. 1 and calculating the Majorana number directly. Nontrivial phases with exhibits MBS at zero energy, as in Fig. 2(b), where we show the energy spectra for , calculated by direct diagonalization of Eq. 1 with open nonperiodic boundary conditions.
For amplitude-modulated fields , the Hamiltonian in Eq. 2 depends periodically on the phase-offset , which can be regarded as an additional synthetic (nonspatial) dimension. The 1D chain is thus embedded in a 2D parameter space, which coincides with a synthetic BZ spanned by the momentum and by the phase-offset . Topological phases in 2D and symmetry class D are described by a topological invariant. We notice that the total Chern number is zero due to PH symmetry. Therefore, to describe the nontrivial globally gapped phases of the model, we shall introduce the PH Chern number, defined as the PH analogue of the spin Chern numberkane_quantum_2005 ; kane__2005 ; sheng_spin_2005 ; sheng_quantum_2006 ; bernevig_quantum_2006 . For any globally gapped phase , which does not close when the superconducting paring is adiabatically turned off , we define
[TABLE]
where are the total Berry curvatures in the synthetic BZ, defined respectively for the two PH sectors of the Hamiltonian in Eq. 2 as a sum over all bands with . Due to PH symmetry, the total Berry curvatures are , and the Chern number vanishes, . The PH Chern number can be nonzero, and it is given by
[TABLE]
The PH Chern number is thus an even integer due to PH symmetry. Notice that the PH Chern number is well-defined only if the phase with can be continuously mapped into a phase with , without closing the global PH gap . Only in this case indeed, the phase is homeomorphic to the phase , where the Hamiltonian becomes block-diagonal in the PH sectors, and the PH Berry curvatures become well-defined. As a counterexample, notice the PH Chern number is not well-defined for the nontrivial phase , where the gap closes for .
If the helical and applied fields are comparable, the model may realize a nontrivial phase characterized by a nonzero PH Chern number, as shown in Fig. 2(a). Using the Fukui-Hatsugai-Suzuki numerical methodfukui_chern_2005 applied separately in the PH sectors, we find that the PH Chern number of this globally gapped phase is . The emergence of a nontrivial phase can be understood in terms of a band inversion induced by the applied field. Considering a continuous transformation , , and , each of the PH and spin-up and spin-down sectors of the Hamiltonian in Eq. 2 reduce to an Harper-Hofstadter Hamiltonian of spinless electrons on a 1D lattice with harmonic potential , with for spin up and down, respectively. Thus, if the transformation does not close the global PH gap, the PH Chern number can be obtained as the sum of the corresponding Chern numbers of the Hofstadter butterfly. Since opposite gaps of the butterfly have opposite Chern numbers, spin-up and spin-down contributions have opposite signs. Hence, if we define and as the intraband indices of the particle spin-up and spin-down sectors of Eq. 2, using the diophantine equation characterizing the Hofstadter butterfly Chern numbers, Eq. 4 yields
[TABLE]
where
[TABLE]
Here, are the Chern numbers labeling each of the intraband gaps of the Hofstadter butterflybellissard_noncommutative_1994 ; osadchy_hofstadter_2001 . Since the Hofstadter Chern numbers take all possible integer values , the PH Chern number can take all possible even integer values . At zero applied field , spin-up and spin-down bands are degenerate, and thus , resulting in a trivial phase . However, spin degeneracy breaks at finite applied fields, and thus bands with can align at zero energy. Hence, the band inversion driven by the applied field can induce a nontrivial phase with .
These nontrivial phases correspond to the presence of nontrivial ABS localized at the edges. Nontrivial ABS are midgap excitations, and are completely PH and spin polarized. Due to bulk-edge correspondencehatsugai_chern_1993 ; imura_bulk-edge_2018 , each edge exhibits a number of particle-like edge states, and the same number of hole-like edge states, which are PH conjugates one of the other. This has to be contrasted with MBS, which appear as a single zero-energy fermionic state localized at two opposite edges, and which are consequently PH symmetric, i.e., being their own PH conjugates. Figure 2(c) shows the energy spectra in the nontrivial phase (with ) calculated by direct diagonalization of Eq. 1 with open nonperiodic boundary conditions. The spectra show PH-symmetric, nontrivial ABS inside the PH gap, with 2 edge states for each boundary of the chain. These ABS are protected by PH symmetry, and robust against perturbations which do not close the gap and do not break PH symmetry (see Supplemental Materialsupp ).
Despite the fundamental difference between MBS and nontrivial ABS, there are some similarities that need to be emphasized. Nontrivial ABS are midgap excitations, and can have zero energy only for fine-tuned values of the phase-offset. However, their energies can be lower than the experimental resolution, and thus the resulting near-zero bias peak can be erroneously attributed to MBS. Most importantly, being topologically protected, they can materialize only concomitantly with the closing and reopening of the PH gap. Hence, the simultaneous probe of bulk and edge conductance, with the observation of the closing of the gap accompanied by the emergence of a zero-bias peak at the edgesgrivnin_concomitant_2019 , cannot be considered as conclusive evidence of MBS. However, nontrivial ABS do not necessarily appear simultaneously with the same energy at the two opposite edges of the nontrivial phase, contrarily to the case of MBS. In order to highlight the differences and similarities between nontrivial ABS and MBS, we show in Fig. 3 the spectra and the local density of states (LDOS) as a function of the applied field through the two nontrivial phases and , calculated as with the unperturbed Green’s function. As shown, both the and the nontrivial phases are realized, respectively at low and large applied fields , respectively with MBS and nontrivial ABS localized at the edges. The closing and reopening of the global PH gap coincides with the appearance of nontrivial ABS. Notice that, contrarily to the case of MBS, the energies of the 2 nontrivial ABS at the opposite edges are uncorrelated. Moreover, whereas MBS have equal spectral weights in the PH sectors (they are PH symmetric), nontrivial ABS are completely PH and spin polarized.
In summary, we found that in the presence of amplitude-modulated fields, a 1D superconductor may exhibits two distinct kinds of nontrivial phases corresponding to two distinct topological invariants, i.e., the Majorana number and the PH Chern number, defined respectively in the 1D and in a synthetic 2D BZ. These nontrivial phases exhibits two distinct kind of edge states, i.e., MBS and nontrivial ABS, with remarkably different properties. However, their similarities may hinder the detection of Majorana states in magnetic atom chains, in particular in the regime of large applied fields.
This work opens several directions for future research. First, nontrivial ABS can be realized in nanowires with amplitude-modulated fields, induced by, e.g., arrays of nanomagnetskjaergaard_majorana_2012 ; klinovaja_transition_2012 ; maurer_designing_2018 or magnetic film substrates in the stripe phasemohanta_electrical_2019 ; zhou_tunable_2019 , where they may exhibit distinctive signatures, e.g., in the differential conductance and the Josephson current. Moreover, in cold atoms, this model may realize a PH Thouless pump and the direct manipulation of the PH degree of freedom, analogously to the electron spin in spintronics. Finally, the concept of double dimensionality and of the coexistence of different topological phases can be extended to other contiguous entries of the periodic table of topological phases, or to higher-order topological insulatorsschindler_higher-order_2018 .
We thank Daisuke Inotani for useful discussions and suggestions, and the anonymous reviewers whose comments have greatly improved this manuscript. This work is supported by the Ministry of Education, Culture, Sports, Science, and Technology (MEXT)-Supported Program for the Strategic Research Foundation at Private Universities “Topological Science” (Grant No. S1511006). The work of M.N. is also supported in part by the Japan Society for the Promotion of Science (JSPS) Grant-in-Aid for Scientific Research (KAKENHI) Grants No. 16H03984 and No. 18H01217 and by a Grant-in-Aid for Scientific Research on Innovative Areas “Topological Materials Science” (KAKENHI Grant No. 15H05855) from MEXT of Japan.
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