# Analysis of incubation time preceding the Ga-assisted nucleation and growth of GaAs nanowires on Si(111)

## TL;DR

This study investigates the incubation time before Ga-assisted GaAs nanowire growth on Si(111), revealing how fluxes and temperature influence nucleation delays and nanowire density, with a developed model explaining these dependencies.

## Contribution

The paper introduces a nucleation model that accurately predicts incubation times and their dependence on fluxes and temperature for GaAs nanowire growth on Si(111).

## Key findings

- Incubation time increases with decreasing As flux.
- Incubation time becomes infinite at a minimum As flux and high temperature.
- Nanowire density varies strongly with temperature.

## Abstract

The incubation time preceding nucleation and growth of surface nanostructures is interesting from a fundamental viewpoint but also of practical relevance as it determines statistical properties of nanostructure ensembles such as size homogeneity. Using in situ reflection high-energy electron diffraction, we accurately deduce the incubation times for Ga-assisted GaAs nanowires grown on unpatterned Si(111) substrates by molecular beam epitaxy under different conditions. We develop a nucleation model that explains and fits very well the data. We find that, for a given temperature and Ga flux, the incubation time always increases with decreasing As flux and becomes infinite at a certain minimum flux, which is larger for higher temperature. For given As and Ga fluxes, the incubation time always increases with temperature and rapidly tends to infinity above 640 {\deg}C under typical conditions. The strong temperature dependence of the incubation time is reflected in a similar variation of the nanowire number density with temperature. Our analysis provides understanding and guidance for choosing appropriate growth conditions that avoid unnecessary material consumption, long nucleation delays, and highly inhomogeneous ensembles of nanowires. On a more general ground, the existence of a minimum flux and maximum temperature for growing surface nanostructures should be a general phenomenon pertaining for a wide range of material-substrate combinations.

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Source: https://tomesphere.com/paper/1907.04249