A Novel Option for Waste Tire Rubber Reutilization: Refrigerant in Solid-State Cooling Devices

TL;DR

This study explores using waste tire rubber as a refrigerant in solid-state cooling devices, demonstrating significant barocaloric effects and faster thermal exchange, offering a sustainable recycling and cooling solution.

Contribution

It introduces waste tire rubber as a novel barocaloric refrigerant material, showing its potential for efficient, sustainable solid-state cooling applications.

Findings

WTR exhibits giant adiabatic temperature and entropy changes.

WTR-based materials outperform many existing barocaloric materials.

Pure WTR shows faster thermal exchange than vulcanized natural rubber.

Abstract

Management of discarded tires is a compelling environmental issue worldwide. Although several approaches have been developed to recycle waste tire rubbers, their application in solid-state cooling is still unexplored. Considering the high barocaloric potential verified for elastomers, the use of waste tire rubber (WTR) as refrigerant in solid-state cooling devices is very promising. Here, we investigated the barocaloric effects in WTR and polymer blends made of vulcanized natural rubber (VNR) and WTR, in order to evaluate its feasibility for solid-state cooling technologies. The adiabatic temperature change and the isothermal entropy change reach giant values, as well as the performance parameters, being comparable or even better than most barocaloric materials in literature. Moreover, pure WTR and WTR-based samples also present a faster thermal exchange than VNR, consisting in an additional advantage of using these discarded materials. Thus, the present findings evidence the encouraging perspectives of employing waste rubbers in solid-state cooling based on barocaloric effect, contributing in both the recycling of polymers and the sustainable energy technology field.