# Probing weakly hybridized magnetic molecules by spin-polarized tunneling

## TL;DR

This study uses spin-polarized tunneling microscopy to analyze the magnetic properties of a single paramagnetic molecule on a weakly interacting substrate, revealing how its magnetic behavior depends on local hybridization effects.

## Contribution

It demonstrates a method to probe magnetic properties of individual molecules on inert substrates, highlighting the influence of local hybridization on magnetic behavior.

## Key findings

- Magnetic response varies with molecule position on moire pattern
- Local magnetization curves and spin spectra obtained for single molecules
- Magnetic behavior depends on hybridization between molecule and substrate

## Abstract

Advances in molecular spintronics rely on the in-depth characterization of the molecular building blocks in terms of their electronic and, more importantly, magnetic properties. For this purpose, inert substrates that interact only weakly with adsorbed molecules are required in order to preserve their electronic states. Here, we investigate the magnetic-field response of a single paramagnetic 5,5-dibromosalophenatocobalt(II) (CoSal) molecule adsorbed on a weakly interacting magnetic substrate, namely Fe-intercalated graphene (GR/Fe) grown on Ir(111), by using spin-polarized scanning tunneling microscopy and spectroscopy (SP-STM/STS). We have obtained local magnetization curves, spin-dependent tunneling spectra, and spatial maps of magnetic asymmetry for a single CoSal molecule, revealing its magnetic properties and coupling to the local environment. The distinct magnetic behavior of the Co-metal center is found to rely strictly on its position relative to the GR/Fe moire structure, which determines the level of hybridization between the GR/Fe surface pi-system, the molecular ligand pi-orbitals and the molecular Co-ion d-orbital.

---
Source: https://tomesphere.com/paper/1906.04677