# Atomic nonaffinity as a predictor of plasticity in amorphous solids

## TL;DR

This paper introduces atomic nonaffinity as a predictive indicator for plasticity in amorphous solids, enabling identification of shear transformation zones and their orientations to forecast plastic events.

## Contribution

It derives a new atomic nonaffinity measure from potential energy landscape perturbation analysis, improving prediction of plasticity locations and orientations in amorphous solids.

## Key findings

- Atomic nonaffinity effectively locates shear transformation zones.
- It reveals the intrinsic softest shear orientation.
- The method predicts protocol-dependent plastic responses.

## Abstract

Structural heterogeneity of amorphous solids present difficult challenges that stymie the prediction of plastic events, which are intimately connected to their mechanical behavior. Based on a perturbation analysis of the potential energy landscape, we derive the atomic nonaffinity as an indicator with intrinsic orientation, which quantifies the contribution of an individual atom to the total nonaffine modulus of the system. We find that the atomic nonaffinity can efficiently characterize the locations of the shear transformation zones, with a predicative capacity comparable to the best indicators. More importantly, the atomic nonaffinity, combining the sign of third order derivative of energy with respect to coordinates, reveals an intrinsic softest shear orientation. By analyzing the angle between this orientation and the shear loading direction, it is possible to predict the protocol-dependent response of plastic events. Employing the new method, the distribution of orientations of shear transformation zones in a model two-dimensional amorphous solids can be measured. The resulting plastic events can be understood from a simple model of independent plastic events occurring at variously oriented shear transformation zones. These results shed light on the characterization and prediction of the mechanical response of amorphous solids.