# Large memcapacitance and memristance at Nb:SrTiO$_{3}$ / La$_{0.5}$Sr$_{0.5}$Mn$_{0.5}$Co$_{0.5}$O$_{3-\delta}$ Topotactic Redox Interface

## TL;DR

This paper demonstrates a large memcapacitive response at a Nb:SrTiO3/LSMCO interface, leveraging topotactic redox properties to enhance neuromorphic device functionalities with potential for disruptive nanoelectronics.

## Contribution

It introduces a novel memristive interface with significant memcapacitive effects based on topotactic redox in LSMCO, advancing neuromorphic device technology.

## Key findings

- Memcapacitive effect ratio C_HIGH/C_LOW ~ 100 at 150 kHz
- Switchable n-p diode at the Nb:SrTiO3/LSMCO interface
- Potential for neuromorphic computing applications

## Abstract

The possibility to develop neuromorphic computing devices able to mimic the extraordinary data processing capabilities of biological systems spurs the research on memristive systems. Memristors with additional functionalities such as robust memcapacitance can outperform standard devices in key aspects such as power consumption or miniaturization possibilities. In this work, we demonstrate a large memcapacitive response of a perovskite memristive interface, using the topotactic redox ability of La$_{0.5}$Sr$_{0.5}$Mn$_{0.5}$Co$_{0.5}$O$_{3-\delta}$ (LSMCO, 0 $\leq$ $\delta$ $\leq$ 0.62). We demonstrate that the multi-mem behaviour originates at the switchable n-p diode formed at the Nb:SrTiO3/LSMCO interface. We found for our Nb:SrTiO$_{3}$/LSMCO/Pt devices a memcapacitive effect C$_{HIGH}$/C$_{LOW}$ ~ 100 at 150 kHz. The proof-of-concept interface reported here opens a promising venue to use topotactic redox materials for disruptive nanoelectronics, with straightforward applications in neuromorphic computing technology.

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Source: https://tomesphere.com/paper/1905.05711