# Standing in the shadow of dark gas: ALMA observations of absorption from dark CO in the molecular DNM of Chamaeleon

## TL;DR

This study uses ALMA observations to detect CO absorption in the dark molecular gas of Chamaeleon, revealing low CO column densities that explain the absence of emission detection and shedding light on early CO formation stages.

## Contribution

First detection of CO absorption in dark molecular gas regions of Chamaeleon, linking low CO abundance to early formation stages in diffuse molecular gas.

## Key findings

- CO absorption detected with low column densities below emission detection limits
- Dark neutral medium primarily due to small CO columns at the HI/H2 transition
- CO/H2 ratios comparable to UV absorption measurements in similar environments

## Abstract

% context We had detected J=1-0 HCO+ absorption in 12 directions lacking detected CO emission in the outskirts of the Chamaeleon complex and on 1 sightline with integrated CO emission 2.4 K-\kms. 8 sightlines had a much larger mean column density of dark neutral medium (DNM)-gas not represented in H I or CO emission-and were found to have much higher mean molecular column density. The 5 other sightlines had little or no DNM and were found to have much smaller but still detectable N(HCO+). % aims To determine N(CO) along previously-observed Chamaeleon sightlines and to determine why CO emission was not detected in directions where molecular gas is present. % methods We took \cotw\ J=1-0 absorption profiles on 5 sightlines having higher DNM and HCO+ column densities and 1 sightline with smaller N(DNM) and N(HCO+). We converted the integrated HCO+ optical depths to N(H2) in the weak-excitation limit using N(HCO+)/N(H2)$=3\times10^{-9}$ and converted the integrated CO optical depths \ICO\ to CO column density N(CO) $= 1.861\times 10^{15}\pcc \ICO^{1.131}$ as found along comparable lines of sight previously studied in J=1-0 and J=2-1 CO absorption&emission. %results CO absorption was detected along the 5 sightlines in the higher-DNM group, with CO column densities $4\times 10^{13} \pcc<$ N(CO) $<10^{15}\pcc$ that are generally below the detectability limit of CO emission surveys. %conclusions In the outskirts of the Chamaeleon complex, the presence of molecular DNM resulted primarily from small CO column densities at the onset of CO formation around the HI/\HH\ transition in diffuse molecular gas. CO relative abundances N(CO)/N(H2) $< 2\times 10^{-6}$ in the outskirts of Chamaeleon are comparable to those seen in UV absorption toward early-type stars, including in Chamaeleon.