# Electrochemical properties of Na$_{0.66}$V$_4$O$_{10}$ nanostructures as cathode material in rechargeable batteries for energy storage applications

## TL;DR

This study investigates Na$_{0.66}$V$_4$O$_{10}$ nanostructures as cathodes in rechargeable batteries, demonstrating good cycling stability and insights into vacancy formation energies, highlighting their potential for energy storage.

## Contribution

It provides new electrochemical data on Na$_{0.66}$V$_4$O$_{10}$ nanostructures and explores their vacancy formation energies using density functional theory.

## Key findings

- Good cycling stability with specific capacities of 80 and 30 mAh g$^{-1}$ at different current densities.
- Redox peaks at ~3.1 and 2.6 V indicating two-phase transition reactions.
- Higher capacity observed with Li anode but with faster decay.

## Abstract

We report the electrochemical performance of nanostructures of Na$_{0.66}$V$_4$O$_{10}$ as cathode material for rechargeable batteries. The Rietveld refinement of room temperature x-ray diffraction pattern shows the monoclinic phase with C2/m space group. The cyclic voltammetry curves of prepared half-cells exhibit redox peaks at ~3.1 and 2.6~V, which are due to two-phase transition reaction between V$^{5+/4+}$ and can be assigned to the single step deintercalation/intercalation of Na-ion. We observe a good cycling stability with specific discharge capacity (measured vs. Na$^+$/Na) between 80 ($\pm$2) and 30 ($\pm$2) mAh g$^{-1}$ at a current density 3 and 50~mA g$^{-1}$, respectively. The electrochemical performance of Na$_{0.66}$V$_4$O$_{10}$ electrode was also tested with Li anode, which showed higher capacity, but decay faster than Na. Using density functional theory, we calculate the Na vacancy formation energies; 3.37~eV in the bulk of the material and 2.52~eV on the (100) surface, which underlines the importance of nanostructures.