# The Correlated Electronic States of a few Polycyclic Aromatic Hydrocarbons: A Computational Study

## TL;DR

This study computationally investigates the electronic states of various polycyclic aromatic hydrocarbons (PAHs), revealing their non-fluorescent nature and limited potential for solar cell applications due to their electronic state configurations.

## Contribution

It provides a systematic analysis of PAHs' electronic states using the Pariser-Parr-Pople model, highlighting their electronic properties and implications for optoelectronic applications.

## Key findings

- 2A state is below the 1B state in studied PAHs
- None of the PAHs are fluorescent in the gaseous phase
- Singlet-triplet gap exceeds half of the singlet-singlet gap

## Abstract

In recent years Polycyclic Aromatic Hydrocarbons (PAHs) have been studied for their electronic properties as they are viewed as nanodots of graphene. They have also been of interest as functional molecules for applications such as light emitting diodes and solar cells. Since last few years varying structural and chemical properties corresponding to the size and geometry of these molecules have been studied both theoretically and experimentally. In this paper, we carry out a systematic study of the electronic states of several PAHs using the Pariser-Parr-Pople model which incorporates long-range electron correlations. In all the molecules studied by us, we find that the 2A state is below the 1B state and hence none of them will be fluorescent in the gaseous phase. The singlet-triplet gap is more than one-half of the singlet-singlet gap in all cases and hence none of these PAHs can be candidates for improved solar cell efficiencies in a singlet fission. We discuss in detail the properties of the electronic states which include bond orders and spin densities (in triplets) of these systems.