# Direct CO2 Electroreduction from Carbonate

## TL;DR

This paper introduces a novel electrolyzer that directly converts carbonate solutions from CO2 capture into syngas, achieving complete carbon utilization and high efficiency, thus streamlining CO2 valorization processes.

## Contribution

It presents a new carbonate electrolyzer design that enables direct CO2 conversion from capture solutions, reducing waste and improving system efficiency.

## Key findings

- Achieved 100% carbon utilization in the system.
- Generated pure syngas with a 3:1 H2 to CO ratio.
- Operated stably for 145 hours at 180 mA cm-2.

## Abstract

The process of CO2 valorization, all the way from capture of CO2 to its electrochemical upgrade, requires significant inputs in each of the capture, upgrade, and separation steps. The gas phase CO2 feed following the capture-and-release stage and into the CO2 electroreduction stage produce a large waste of CO2, between 80 and 95% of CO2 is wasted due to carbonate formation or electrolyte crossover, that adds cost and energy consumption to the CO2 management aspect of the system. Here we report an electrolyzer that instead directly upgrades carbonate electrolyte from CO2 capture solution to syngas, achieving 100% carbon utilization across the system. A bipolar membrane is used to produce proton in situ, under applied potential, which facilitates CO2 releasing at the membrane:catalyst interface from the carbonate solution. Using an Ag catalyst, we generate pure syngas at a 3 to 1 H2 to CO ratio, with no CO2 dilution at the gas outlet, at a current density of 150 mA cm-2, and achieve a full cell energy efficiency of 35%. The direct carbonate cell was stable under a continuous 145 h of catalytic operation at ca. 180 mA cm-2. The work demonstrates that coupling CO2 electrolysis directly with a CO2 capture system can accelerate the path towards viable CO2 conversion technologies.

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Source: https://tomesphere.com/paper/1905.01818