# Out-of-equilibrium electrons lead to record thermionic emission in LaB6 with the Jahn-Teller instability of boron cage

## TL;DR

This study reveals that out-of-equilibrium electrons, coupled with lattice vibrations and Jahn-Teller instabilities in LaB6, are responsible for its record thermionic emission properties, offering insights for designing better electron sources.

## Contribution

It uncovers the role of hot, non-equilibrium electrons coupled to lattice vibrations and Jahn-Teller effects in LaB6's thermionic emission, a novel insight into its physical mechanism.

## Key findings

- Only a small fraction of electrons behave as Drude carriers.
- Up to 70% of electrons are involved in collective oscillations.
- Non-equilibrium electrons determine LaB6's low work function.

## Abstract

Materials with low electron work function are of great demand in various branches of science and technology. LaB6 is among the most effective electron-beam sources with one of the highest brightness of thermionic emission. A deep understanding of the physical mechanisms responsible for the extraordinary properties of LaB6 is required in order to optimize the parameters and design of thermionic elements for application in various electron-beam devices. Motivated by recent experiments on rare earth borides indicating a strong coupling of conduction electrons to the crystal lattice and rare earth ions, we have studied the state of electrons in the conduction band of lanthanum hexaboride by performing infrared spectroscopic, DC resistivity and Hall-effect studies of LaB6 single crystals with different ratios of 10B and 11B isotopes. We find that only a small amount of electrons in the conduction band behave as Drude-type mobile charge carriers while up to 70% of the electrons are far out of equilibrium and involved in collective oscillations of electron density coupled to vibrations of the Jahn-Teller unstable rigid boron cage and rattling modes of La-ions that are loosely bound to the lattice. We argue that exactly these non-equilibrium (hot) electrons in the conduction band determine the extraordinary low work function of thermoemission in LaB6. Our observation may guide future search for compounds with possibly lower electron work function.

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Source: https://tomesphere.com/paper/1904.07132